1,2-Bis[(2S,5S)-2,5-Diisopropylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate 1,2-双[(2S,5S)-2,5-二异丙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)

CAS 1000393-36-1 MFCD07369040

化学结构图

1000393-36-1
SMILES:

化学属性

Mol. FormulaC34H56BF4P2Rh
Mol. Weight716.47
Stabilityair sensitive
Appearance red-orange xtl.

别名和识别编码

Chemical Name1,2-Bis[(2S,5S)-2,5-Diisopropylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate
MDL NumberMFCD07369040
CAS Number1000393-36-1
Synonym 1,2-双[(2S,5S)-2,5-二异丙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)
Chemical Name Translation1,2-双[(2S,5S)-2,5-二异丙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)
PubChem Substance ID329762003
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes

相关文献及参考

  • 1. Fox, M. E.; et al., Large-Scale Synthesis of a Substituted D-Phenylalanine Using Asymmetric Hydrogenation Org. Process Res. Dev. 15 , 1163-1171, (2011)
  • 2. Qiu, L.; et al., Enantioselective hydrogenation of a-aminomethylacrylates containing a free N-H group for the synthesis of ß-amino acid derivatives Proc. Natl. Acad. Sci. U. S. A. 104 , 16787-16792, (2007)

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类


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