p-Xylene 对二甲苯

CAS 106-42-3 MFCD00008556

化学结构图

106-42-3
SMILES: CC1CCC(C)CC1

化学属性

Mol. FormulaC8H10
Mol. Weight106.17
Refractive index1.4940 to 1.4980
Boiling Point-
Density0.861
Melting Point12-13
Flash Point25°C
TSCAYes
Autoignition Point984 °F
Vapor Density3.7 (vs air)
Vapor Pressure9 mmHg ( 20 °C)
Solubility不溶于水，可混溶于乙醇、乙醚、氯仿等多数有机溶剂。
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical Namep-Xylene
Synonym 4-Methyltoluene {LY} 4-Methyltoluene Chromar P-XYLENE P-XYLENE, 99+%, H p-Xylene {} {LY} 4-Methyltoluene {} {} {LY} 4-Methyltoluene {} {} {} {LY} 4-Methyltoluene {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methyltoluene {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number106-42-3
PubChem Substance ID87577904
EC Number203-396-5
Beilstein Registry Number1901563
MDL Number-
Reaxys-RN1901563
Merck Number10081
Chemical Name Translation对二甲苯
Wiswesser Line Notation1R D1
LabNetwork Molecule IDLN00164096
InChIInChI=1S/C8H10/c1-7-3-5-8(2)6-4-7/h3-6H,1-2H3
Canonical SMILESCC1=CC=C(C)C=C1
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品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Anhydrous Solvents, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents, Sure/Seal Bottles
  • {SNA} Additional Standards, Alpha Sort, Analytical Standards,
  • Analytical Reagents, Analytical Reagents for General Use, Analytical Standards, Analytical/Chromatography, Aromatics, Carthamus tinctorius (Safflower oil), Chemical Class, Nutrition Research, Phytochemicals by Plant (Food/Spice/Herb), Puriss p.a., T-Z, Puriss p.a.
  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, Pharmaceutical Secondary Standards, Pharmaceutical Standards
  • {SNA} Addit

产品应用

  • 校准仪器和装置；评价方法；工作标准；质量保证/质量控制；

相关文献及参考

  • Merck:14,10081
  • Merck:14,10081 Beilstein: 5,IV,951
  • Short: II/25D
  • Short: II/27B

安全信息

GHS Symbol
WGK Germany2
Hazard Codes
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H312 Harmful in contact with skin 皮肤接触有害
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H312+H332
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSZE2625000
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P302+P352+P332+P313+P362+P364
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P304+P340+P312
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P337+P313
  • P308+P311
  • P241+P242+P243
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word
UN Number UN1307
Risk Statements
  • R10 Flammable 易燃
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R38 Irritating to skin 刺激皮肤
Safety Statements
Packing GroupIII
Storage condition 0-6°C 4°C 储存温度2-8℃ 密封阴凉保存。
Hazard Class3
Warnings 危化品目录(2015) 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent -

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YAKUD5 Gekkan Yakuji.  Pharmaceuticals Monthly.  (Yakugyo Jihosha, Inaoka
   Bldg., 2-36 Jinbo-cho, Kanda, Chiyoda-ku, Tokyo 101, Japan)  V.1-   1959-
   Volume(issue)/page/year: 22,883,1980

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/k

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROU

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4550 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - chronic pulmonary edema
   Liver - other changes
   Blood - changes in cell count (unspecified)
REFERENCE :
   36YFAG "Biological Reactive Intermediates, Formation, Toxicity and
   Inactivation, Proceedings of the International Conference, Turku, Finland,
   1975," Jollow, D.J., et al., eds., New York, Plenum Pub. Corp., 1977
   Volume(issue)/page/year: -,302,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2450 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   58,106,1985

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 150 mg/m3/24H
SEX/DURATION            : female 7-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - extra-embryonic structures
   (e.g., placenta, umbilical cord)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 18,61,1980

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3000 mg/m3/24H
SEX/DURATION            : female 7-14 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 18,61,1980

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 7 gm/m3
SEX/DURATION            : female 7-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 34,223,1986

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 30

Restrict -

其他信息

  • {Chemi
  • 毒性分级:中毒
  • 方法一:1.石油二甲苯、煤焦油二甲苯中，都含有相当量的对二甲苯。
  • Sigma Aldrich:106-42-3(sigmaaldrich)
  • 防护措施:对小鼠致死浓度为15～35mg/L。参见“二甲苯”。
  • 蒸气密度:3.7 (vs air)
  • 爆炸物危险特性:与空气混合可爆
  • 对二甲苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80139228 对二甲苯;1,4-二甲基苯 500ml 17.2元 2011/08/23 40063990 对二甲苯;1,4-二甲基苯 2ml 65元 2011/04/16 S0649 对二甲苯(1mg/ml的甲醇溶液)[用于水分析] p-Xylene (1mg/ml in Methanol) [for Water Analysis] 1ML 198元
  • 图谱信息:对二甲苯(106-42-3)核磁图( 13 CNMR) 对二甲苯(106-42-3)红外图谱(IR1) 对二甲苯(10
  • 类别:易燃液体
  • TCI Shanghai:对二甲苯[泰格密闭闪点测试流动液] p-Xylene [Tag Closed Flash Point Check Fluid],>;99.0%(GC)(106-42-3)
  • 职业标准:TLV-TWA 100 PPM (440 毫克/ 立方米); STEL 150 PPM(655 毫克/ 立方米)
  • 用途六:溶剂。有机合成。气相色谱分析标准。用于生产对苯二甲酸，进而生产对苯二甲酸乙二醇酯；丁二醇酯等聚酯树脂。聚酯树脂是生产涤纶纤维；聚酯薄片，聚酯中空容器的原料。绦纶纤维是我国目前第一大合成纤维。也用作涂料；染料和农药等的原料.用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。
  • MOL 文件:106-42-3.mol
  • 急性毒性:口服- 大鼠 LD50: 5000 毫克/ 公斤; 腹注- 小鼠 LD50: 2110 毫克/ 公斤
  • Acros Organics:对二甲苯 p-Xylene, pure, 99%(106-42-3)
  • 重要的有机化工原料:对二甲苯是一种重要的有机化工原料，主要用于生产对二苯甲酸(PTA)、对苯二甲酸二甲酯(DMT)和对苯二甲酸乙二醇酯(PET)，进而生产聚对苯二甲酸酯(涤纶)，还可用作溶剂以及医药、香料、油墨等行业的生产原料。目前我国已经成为世界上生产和消费对二甲苯的第一大国，最初，对二甲苯是从石脑油催化重整获得的石油芳烃中提取得到的，后来随着石油化工和煤炭焦化行业的发展，芳烃转化成为制备对二甲苯最直接最有效的生产手段。工业上通常以甲苯和C9芳烃为原料，采用甲苯歧化和烷基转移、二甲苯异构化、甲苯一甲醇烷基化以及吸附分离等工艺生产对二甲苯。 二甲苯异构化工艺是以不含对二甲苯的C8芳烃为原料，在催化剂的作用下发生异构反应使混合C8芳烃中的对二甲苯浓度达到平衡浓度，从而提高对二甲苯产量。二甲苯异构化技术工业化的约有10种，在芳烃生产上比较有竞争力的主要有UOP公司的Isomer工艺，Axens公司的Octafining工艺以及美国Mobil公司的MHAⅠ工艺。 Isomar工艺使用双功能催化剂（MgAPSO/ZSM-5）将乙苯临氢异构成二甲苯，克服了一带催化剂带来的腐蚀问题。中国石油辽阳石化分公司二期芳烃联合装置即采用该工艺。Axens
  • 上游原料:氢氧化钠 --> 硫酸 --> 二甲苯 --> 间二甲苯 --> 焦油 --> 粗苯 --> 轻苯 --> 吸附剂
  • 外观性质:无色透明液体，有类似甲苯的气味。
  • 用途三:用作生产
  • 低温时凝固成片状或棱柱状结晶。溶于乙醇、乙醚和其他许多有机溶剂，不溶于水。易燃。蒸气能与空气形成爆炸性混合物，爆炸极限1.08%-6.60%（体积）。低毒，半数致死量（大鼠，经口）4300mg/kg。有刺激性。
  • 蒸气压:9 mm Hg ( 20 °C)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent by Application - Solvents
  4. Anhydrous Solvents - Solvent by Application
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Chromatography Reagents & Solvents - Analytical Reagents
  4. LC-NMR Solvents (CHROMASOLV®) - Chromatography Reagents & Solvents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. X - Alphabetic
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Aromatics - Chemical Class
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent by Application - Solvents
  4. ACS and Reagent Grade Solvents - Solvent by Application
  5. ReagentPlus® Solvent Grade Products - ACS and Reagent Grade Solvents
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent by Application - Solvents
  4. HPLC/UHPLC Solvents (CHROMASOLV®) - Solvent by Application
  5. HPLC Grade Solvents (CHROMASOLV®) - HPLC/UHPLC Solvents (CHROMASOLV®)
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent Packaging Options - Solvents
  4. Solvent Bottles - Solvent Packaging Options
  5. Sure/Seal™ Bottles - Solvent Bottles
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  5. T-Z, Puriss p.a. - Puriss p.a.
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂