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• 试剂商城
• 直接询价

分类

• {uni_hamburg} no charge; 1fragment
• {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks

相关文献及参考

• Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
• Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
• Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.

安全信息

GHS Symbol

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 2500 ppb/5M
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Lungs, Thorax, or Respiration - structural or functional change in trachea
   or bronchi
REFERENCE :
   AEHLAU Archives of Environmental Health.  (Heldref Pub., 4000 Albemarle St.,
   NW, Washington, DC 20016)  V.1-    1960-  Volume(issue)/page/year:
   1,343,1960

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 37500 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FATOAO Farmakologiya i Toksikologiya (Moscow).  For English translation, see
   PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2-   
   1939-  Volume(issue)/page/year: 31,238,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 102 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,17,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 49 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - chronic pulmonary edema
REFERENCE :
   AEHLAU Archives of Environmental Health.  (Heldref Pub., 4000 Albemarle St.,
   NW, Washington, DC 20

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 2500 ng/kg
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 48(1),80,1983

其他信息

• MOL 文件:107-11-9.mol
• Acros Organics:丙烯胺（禁运） Allylamine, extra pure, 98+%(107-11-9)
• 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放; 不宜久储, 以防聚合
• 刺激数据:皮肤- 兔子 500 毫克/ 24小时 重度; 眼- 兔子 50 毫克/ 20秒 重度
• F:10
• 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
• 爆炸物危险特性:与空气混合可爆
• 外观性质:无色液体，有强烈的氨味和焦灼味。
• 海关编码:29211980
• 蒸气密度:2 (vs air)
• 类别:易燃液体
• 图谱信息:烯丙胺(107-11-9)质谱(MS) 烯丙胺(107-11-9)核磁图( 13 CNMR) 烯丙胺(107-11-9)红外图谱(IR2) 烯丙胺(107-11-9)红外图谱(IR1) 烯丙胺(107-11-9)核磁图( 1 HNMR)
• 方法一:烯丙基氯与氨反应可制得烯丙胺：反应在带回流装置的设备里进行，使硫代异氰酸丙烯酯与20%盐酸回流反应15h。将反应物浓缩，结晶出现时又加水稀释，然后在滴加碱液的同时将烯丙胺蒸出。收集的粗品可用分馏法精制。
• 下游产品:(R)-1-Boc-3-氨基吡咯烷 --> (R)-3-叔丁氧羰基氨基吡咯烷 --> 氟伐他汀钠 --> 2,2-二溴-3-次氮基丙酰胺 --> 8105 染料印花粘合剂,AF 自交型涂料粘合剂,印染粘合剂 DE,SC-183 涂料印花粘合剂,7601-自交型粘合剂 T/C --> 烯丙基脲
• 上游原料:丙烯酰氯
• 用途一:用作制药中间体、乳液改性剂、有机合成和树脂改性剂、硅产品等的中间体
• 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
• 急性毒性:口服- 大鼠 LD50: 102 毫克/ 公斤; 口服- 小鼠 LD50: 57 毫克/ 公斤
• 用途三:107-11-9（烯丙胺）可用于制药中间体、以及家用化学品、乳液改性剂、有机合成和树脂改性剂、硅产品等的中间体。有报导称，可与血浆聚合生成反渗透腊的聚合物用于密闭的载人宇宙飞船中；也可以作腐蚀抑制剂、催化剂和溶剂等。
• 用途二:用于有机合成，制造树脂及利尿药。
• 职业标准:TWA 5 毫克/ 立方米; STEL 15 毫克/ 立方米
• MSDS 信息:烯丙胺(107-11-9).msds
• Alfa Aesar:丙烯基胺,98+% Allylamine, 98+%(107-11-9)
• 烯丙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 220732500 烯丙胺 Allylamine 98+%, extra pure 250 ML 512元 2010/06/21 220730010 烯丙胺 Allylamine 98+%, extra pure 1 LT 1466元 2010/06/21 220730500 烯丙胺 Allylamine 98+%, extra pure 50 ML 439元
• 参考质量标准:指标 目标值 检测方法 色泽 ≤50 DIN ISO 6271 含量 ≥99.5% GC 水分 ≤0.3% DIN ISO 51777
• 毒性分级:高毒
• 敏感性:Air Sensitive
• 蒸气压:4.09 psi ( 20 °C)
• Sigma Aldrich:107-11-9(sigmaaldrich)