Butyldiglycol 二乙二醇单丁醚

CAS 112-34-5 MFCD00002881

化学结构图

112-34-5
SMILES: CCCCOCCOCCO

化学属性

Mol. FormulaCH3(CH2)3OCH2CH2OCH2CH2OH
Mol. Weight162
Refractive index1.4300 to 1.4340
Boiling Point231
Density0.955
Melting Point-68
Flash Point78°C(lit.)
TSCAYes
Autoignition Point400 °F
Vapor Density5.6 (vs air)
Vapor Pressure30 mmHg ( 130 °C)
Solubility溶于水、油类,易溶于醇、醚。

别名和识别编码

Chemical NameButyldiglycol
Synonym 2-(2-Diethylenglykolmonobutylether) 2-(2-butoxyethoxy)-ethano 2-(2-butoxyetoxy)etanol 2-(2-丁氧基 2-(Β-丁氧乙氧)乙醇 3,6-Dioxa-1-decano BDG-NS BUTOXYDIETHYLENE GLYCOL BUTYL CARBITOL(R) BUTYL DIGOL BUTYLDIGLYCOL Butoxy diethylene glycol Butoxydiethylene glycol Butyl digol Butyldiglycol DIETHYLENE GLYCOL MONO-N-BUTYL ETHER DIGLYCOL M Di(ethylene glycol) butyl ether Diethylenglykolmono-n-butylether Diäthylenglykolmonobutyläther Dowanol DB Ethanol, 2-(2-butoxyethoxy)- Glycol ether DB K 50181 butyldi n-Butyl carbitol {} {} {Chem {} {} {uni_hambu 二乙二醇一丁基醚 二甘醇单丁醚/丁基卡必醇
CAS Number112-34-5
PubChem Substance ID8177
EC Number203-961-6
Beilstein Registry Number1739225
MDL NumberMFCD00002881
Reaxys-RN1739225
Merck Number1557
Chemical Name Translation二乙二醇单丁醚
Wiswesser Line NotationQ2O2O4
LabNetwork Molecule IDLN00195515
InChIInChI=1S/C8H18O3/c1-2-3-5-10-7-8-11-6-4-9/h9H,2-8H2,1H3
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分类

  • {SNA} ReagentPlus, ReagentPlus Solvent Grade Products, ACS and Reagent Grade Solvents, Alcohols, Amber Glass Bottles, Building Blocks, C7 to C8, Carbon Steel Flex-Spout Cans, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Semi-Bulk Solvents, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents
  • {SNA} Alcohols, Buil
  • {SNA} Reagent
  • {uni_hamburg} no charge; alcohol; ether; 1fragment
  • {SNA} Analytical Reagents, Analytical/Chromatography, Application Specific Reagents, Reagents for Surfactant Analysis
  • {SNA} Analytical Reagents, Analytical/Chromatography, Reagents for Surfactant Analysis, 特定应用试剂

产品应用

  • 硝化棉、清漆、印刷墨、油类、树脂等的溶剂。塑料中间体。用于表面活性剂分析

相关文献及参考

  • Short: IV/10A
  • Merck:14,1557
  • Merck:14,1557 Beilstein:1(2)521
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany1
Hazard Codes Xi
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKJ9100000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S2 Keep out of the reach of children 避免儿童触及;
  • S24 Avoid contact with skin 避免皮肤接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
Storage condition 密封阴凉干燥保存。
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JACTDZ Journal of the American College of Toxicology.  (Mary Ann Liebert,
   Inc., 1651 Third Ave., New York, NY 10128)  V.1-12, 1982-1993. Discontinued.
    Volume(issue)/page/year: 12,139,1993

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6050 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 46(2),14,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 850 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
   Kidney, Ureter, Bladder - changes in tubules (including acute renal failure,
   acute tubular necrosis)
   Blood - changes in spleen
REFERENCE :
   FEPRA7 Federation Proceedings, Federation of American Societies for
   Experimental Biology. (Bethesda, MD)  V.1-46, 1942-87.
   Volume(issue)/p

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5660 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOWCC* Dow Chemical Company Reports.  (Dow Chemical USA, Health and
   Environment Research, Toxicology Research Lab., Midland, MI 48640)
   Volume(issue)/page/year: MSD-41

其他信息

  • 方法一:在生产乙二醇单丁醚的过程中乙二醇单丁醚与环氧乙烷反应,副产二乙二醇丁醚。
  • Sigma Aldrich:112-34-5(sigmaaldrich)
  • 二乙二醇丁醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30059260 二乙二醇单丁醚 500ml 65元 2011/04/16 B0699 二乙二醇单丁醚 Diethylene Glycol Monobutyl Ether 25ML 167元 2011/04/16 B0699 二乙二醇单丁醚 Diethylene Glycol Monobutyl Ether 500ML 229元
  • 海关编码:29094300
  • 用途一:用作硝化棉、清漆、印刷墨、油类、树脂等的溶剂及合成塑料的中间体
  • 用途四:硝化棉、清漆、印刷墨、油类、树脂等的溶剂。塑料中间体。
  • MSDS 信息:二乙二醇单丁基醚(112-34-5).msds
  • 蒸气压:30 mm Hg ( 130 °C)
  • 用途二:主要用溶剂,用于涂料、染料、树脂等方面,也用作增塑剂的中间体以及液压制动器液体的稀释剂,此外还用来生产胡椒基丁氧基化合物。该品对鼠口服LD50为6560mg/kg。
  • TCI Shanghai:二乙二醇单丁醚 Diethylene Glycol Monobutyl Ether,>;98.0%(GC)(112-34-5)
  • Alfa Aesar:二乙二醇单正丁醚,99% Diethylene glycol mono-n-butyl ether, 99%(112-34-5)
  • 外观性质:无色液体,微具有丁醇气味。
  • 下游产品:增效醚 --> 二乙二醇丁醚醋酸酯
  • 用途三:二乙二醇丁醚(112-34-5)主要用作涂料、印刷油墨、图章用印台油墨、油类、树脂等的溶剂,也可用作金属洗涤剂、脱漆剂、脱润滑油剂、汽车引擎洗涤剂、干洗溶剂、环氧树脂溶剂、药物萃取剂;用作乳胶漆的稳定剂、飞机涂料的蒸发抑制剂、高温烘烤瓷漆的表面加工改进剂等。
  • 微有丁醇气味。易溶于乙醇和乙醚,溶于水、其他有机溶剂及油类。半数致死量(大鼠,经口)6.56g/kg。有刺激性。
  • 蒸气密度:5.6 (vs air)
  • 图谱信息:二乙二醇丁醚(112-34-5)红外图谱(IR1) 二乙二醇丁醚(112-34-5)核磁图( 1 HNMR) 二乙二醇丁醚(112-34-5)质谱(MS) 二乙二醇丁醚(112-34-5)Raman光谱 二乙二醇丁醚(112-34-5)红外图谱(IR2) 二乙二醇丁醚(112-34-5)核磁图( 13 CNMR)
  • Acros Organics:二甘醇单丁醚/丁基卡必醇 2-(2-Butoxyethoxy)ethanol, 99+%(112-34-5)
  • 检测方法:GC,NMR
  • 上游原料:乙醇 --> 甲醇 --> 正丁醇 --> 乙二醇单丁醚
  • MOL 文件:112-34-5.mol

系列性分类