1,3-Propane Sultone 1,3-丙烷磺内酯

CAS 1120-71-4 MFCD00005355

化学结构图

1120-71-4
SMILES: O=S1(=O)CCCO1

化学属性

Mol. FormulaC3H6O3S
Mol. Weight122
Boiling Point180
Density1.392
Melting Point30-33
Flash Point>110°(230°F)
TSCAYes
SolubilitySoluble in water (100 mg/ml), chloroform, esters, methanol, and aromitic hydrocartions.
Stability对湿度敏感

别名和识别编码

Chemical Name1,3-Propane Sultone
CAS Number1120-71-4
Synonym 1,3-丙烷磺酸内酯 3-hydroxy-1-propanesulfonicacidw-sultone (1,2)oxathiolane 2,2-dioxide 3-Hydrox PROPANE SULTONE γ-Propane sultone 3-hydroxy-1-propanesulphonicacidsulfone 1,2-Oxathiolane, 2,2-dioxide 1,3-丙磺酸内酯 NSC 42386 Prop 3-HYDROXY-1-PROPANESULFONIC ACID SULTONE 1-Propanesulfonic acid, 3-hydroxy-γ-sultone 3-Hydroxy-1-propanesulfonic acid gamma-sultone 1,3-propanesultone 3-hydroxy-1-propanesulphonicacidsultone RCRA waste number U193 1-Propanesulfonic acid-3-hydroxy-gamma-sultone 3-hydroxy-1-propanesulfonic acid w-sultone {uni_hamburg 1,2-oxathrolane2,2-dioxide 1,2-oxathiolane 2,2-dioxide {u 1-Propanesulfonic acid, 3-hydroxy-, gamma-sultone 3-Hydroxy-1-propanesulfonic Acid Sultone 丙磺酸内酯 3-Hydroxy-1-propanesulfonic Acid ?-Sultone 3-HYDROXYPROPANESULFONIC ACID SULTONE 3-Hydroxy-1-propanesulfonic acid, sultone 1,2-oxathiolane-2,2-dioxide 1,2-Oxathiolane 2,2-dioxide; 3-Hydroxy-1-propanesulfonic acid g 3-Hydroxy-1-propanesulphonic acid sulfone 1-propanesulfonicacid-3-hydr 3-Hy 3-Hydroxy- 1,3-Propane sultone 1,3-Propansulton 3-Hydroxypropansulfonsäure-Y-sulton {uni_h 3-HYDROXY-1-PROPANESULFONIC ACID GAMMA-SULTONE 1,3-丙烷磺内酯 3-Hydroxy-1-propane sulfonic sultone 1-propanesulfonicacid-3-hydroxy-gamma-sultone[qr] 1-Propanesulfonic acid, 3-hydroxy-, γ-sultone 1,3-PROPANESULTONE 3-Hydroxy-1-propanesulphonic acid sultone 3-hydroxy-1-propanesul
PubChem Substance ID87574552
EC Number214-317-9
Beilstein Registry Number109782
MDL NumberMFCD00005355
Chemical Name Translation1,3-丙烷磺内酯
Reaxys-RN109782
Wiswesser Line NotationT5OSWTJ
LabNetwork Molecule IDLN00226166
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Other Heterocyclic Building Blocks, S-Containing
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Others, S-Containing
  • {uni_hamburg} no charge; oxygen heterocycle; sulfur heterocycle; alicycle; 5ring; 1fragment
  • Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Others, S-Containing

产品应用

  • 1,3-Propanesultone has been used in preparation of poly[2-ethynyl-N-(propylsulfonate)pyridinium betaine],novel poly(4-vinylpyridine) supported acidic ionic liquid catalyst,novel poly(4-vinylpyridine) supported acidic ionic liquid catalyst.

相关文献及参考

  • For a review of the chemistry of sultones, see: Tetrahedron, 43, 1027 (1987).
  • Short: III/38B
  • Short: IV/6
  • Beilstein: 19,IV,4
  • Short: IV/18B
  • Short: IV/8A

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 6.1 T
Hazard statements
  • H301+H311
  • H350 May cause cancer 可能致癌
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSRP5425000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P304 IF INHALED: 如果吸入
  • P304+P340
  • P305+P351+P338
  • P308+P313
  • P332+P313
  • P337+P313
  • P403+P233
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
Packing GroupIII
UN Number 2810
Storage condition Moisture Sensitive 常温 充氩保存
Hazard Class6.1 
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 434 mg/kg/15W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   INTSAO International Surgery.  (International College of Surgeons, 1516 N.
   Lake Shore Dr., Chicago, IL 60610)  V.45-    1966- Volume(issue)/page/year:
   66,161,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   ZEKBAI Zeitschrift fuer Krebsforschung.  (Berlin, Fed. Rep. Ger.)  V.1-75,
   1903-71.  For publisher information, see JCROD7.  Volume(issue)/page/year:
   75,69,1970

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7840 mg/kg/60W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Brain and Coverings - tumors
   Skin and Appendages - tumors
REFERENCE :
   NATUAS Nature.  (Nature Subscription Dept.,

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1100 mg/kg/37W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Peripheral Nerve and Sensation - peripheral nerve tumors
REFERENCE :
   ZEKBAI Zeitschrift fuer Krebsforschung.  (Berlin, Fed. Rep. Ger.)  V.1-75,
   1903-71.  For publisher information, see JCROD7.  Volume(issue)/page/year:
   75,69,1970

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROU

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   NTIS** National Technical

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2140 mg/m3/6H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Vascular - regional or general arteriolar or venous dilation
   Skin and Appendages - hair
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555330

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1000 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 6,139,1976

{hazar

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Behavioral - somnolence (general depressed activity)
   Skin and Appendages - hair
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(i

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 50 nmol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   41,4368,1981

TYPE OF TEST            : Morp

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Serratia marcescens
DOSE/DURATION           : 25 mg/L
REFERENCE :
   ATXKA8 Archiv fuer Toxikologie.  (Berlin, Fed. Rep. Ger.)  V.15-31, 1954-74.
    For publisher information, see ARTODN.  Volume(issue)/page/year: 30,67,1972

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Schizosaccharomyces pombe
DOSE/DURATION           : 7900 umol/L
REFERENCE :
   CBINA8 Chemico-Biological Interactions.  (Elsevier Scientific Pub. Ir

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 10 mg/L
REFERENCE :
   ATSUDG Archives of Toxicology, Supplement.  (Springer-Verlag New York, Inc.,
   Service Center, 44 Hartz Way, Secaucus, NJ 07094)  No.1-    1978-
   Volume(issue)/page/year: 4,41,1980

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 125 mg/L/24H
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 48,337,1977

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 18 mg/kg/48H (Intermittent)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 389,3,1997

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 80 mg/kg
SEX/DURATION            : female 15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   IARCCD IARC Scientific Publications.  (Geneva, Switzerland)  No.1-26,
   1971-78.  For publisher information, see IAPUDO.  Volume(issue)/page/year:
   4,45,1973

其他信息

  • 产品特性:1,3-丙烷磺内酯(1120-71-4)属于功能型精细化工新材料。它能和许多种类的化合物在非常温和的条件下反应，准确的提供磺酸基团，从而赋予这些化合物新的性能（如具有亲水性、抗静电性等特征），是优良的通用型磺化剂，也是合成重要的电镀添加剂中间体PPS、UPS、DPS、MPS、ZPS、POPS、SP等产品的关键原料。水分少于200PPm的高纯度PS可用作锂电池电解液的添加剂，以改善电池的寿命和安全。 1,3-丙烷磺内酯(1120-71-4)也应用于光亮剂、染料、双离子表面活性剂、磺化剂.、锂电池等。
  • 储存方法:存放在阴凉干燥处 有效期2年
  • 用途一:电镀中间体的合成起始原料
  • 用途四:磺化剂，广泛用于医药化工、感光材料、锂电池、生物化学、纺织、润滑、废水处理、表面处理等行业。
  • MOL 文件:1120-71-4.mol
  • 用途三:用作表面活性剂，也用于化妆品的配制及制药工业
  • 图谱信息:1,3-丙烷磺内酯(1120-71-4)核磁图( 1 HNMR) 1,3-丙烷磺内酯(1120-71-4)质谱(MS) 1,3-丙烷磺内酯(1120-71-4)核磁图( 13 CNMR) 1,3-丙烷磺内酯(1120-71-4)红外图谱(IR1) 1,3-丙烷磺内酯(1120-71-4)红外图谱(IR2) 1,3-丙烷磺内酯(1120-71-4)红外图谱(IR3)
  • F:21
  • 上游原料:四氢呋喃 --> 二氯甲烷 --> 三乙胺 --> 正丁基锂 --> 氮 --> 二氧化碳 --> 亚硫酸氢钠 --> 甲基磺酰氯 --> 1,3-丙二醇
  • Sigma Aldrich:1120-71-4(sigmaaldrich)
  • 用途二:用作医药中间体，也用于制革、油墨及增感染料合成
  • 参考质量标准:色度（APHA)<=50 色谱纯度（GC)>99.9% 电池用（ED）水分（Karl-Fisher)<=70PPm 电镀用（ES)水分（Karl-Fisher）<=0.5%
  • 1,3-丙烷磺内酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw020005 1，3-丙烷磺酸内酯 100g 400元 2011/04/16 P0324 丙磺酸内酯 Propane Sultone 500G 3260元 2011/04/16 P0324 丙磺酸内酯 Propane Sultone 25G 354元
  • TCI Shanghai:丙磺酸内酯 Propane Sultone,>;99.0%(GC)(1120-71-4)
  • MSDS 信息:1,2-Oxathiolane 2,2-dioxide(1120-71-4).msds
  • 敏感性:Moisture Sensitive
  • Alfa Aesar:1,3-丙磺内酯,99% 1,3-Propanesultone, 99%(1120-71-4)
  • 外观:无色至淡黄色液体(低温结晶)
  • 下游产品:酸性镀铜光亮剂 --> N-(1-萘)-3-氨基丙磺酸钠盐 --> 3-氯丙烷磺酰氯

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  5. S-Containing - Others
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Functional Group 官能团索引
  2. sulfonic acid ester