1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic anhydride 1,4,5,6,7,7-六氯-5-降冰片烯-2,3-二甲酸酐

CAS 115-27-5 MFCD00080438

化学结构图

115-27-5
SMILES: O=C1OC(=O)C2C1C1(Cl)C(Cl)=C(Cl)C2(Cl)C1(Cl)Cl

化学属性

Mol. FormulaC9H2Cl6O3
Mol. Weight371
Melting Point235.0 to 240.0 deg-C
Density1.730
TSCAYes
Vapor Density13 (vs air)
Solubility不溶
Appearance 白色结晶。熔点231-235℃。溶解度（g/100g）：苯为40.4，已烷4.5，丙酮127.0，四氯化碳6.7，微溶于水并水解成氯桥酸。

别名和识别编码

Chemical Name1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic anhydride
Synonym 1,4,5,6,7,7-六氯二环(2,2,1)-5-庚烯-2,3-二羧酸酐 4,7-Methanoisobenzofuran-1,3-dione, 4,5,6,7,8,8-hexachloro-3a,4,7,7a-tetrahydro- 4,5,6,7,8,8-六氯-3A,4,7,7A-四氢-4,7-亚甲基异苯并呋喃-1,3 氯菌酸酐 {Chemical 1,4,5,6,7,7-HEXACHLORO-5-NORBORNENE-2,3-DICARBOXYLIC ANHYDRIDE PERCHLOROBICYCLO (2.2.1)-5-HEPTENE-2,3-DICARBOXYLIC ANHYDRIDE HEXACHLOROENDOMETHYLENE TETRAHYDROPHTHALIC ANHYDRIDE 氯茵酸酐 1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic Anhydride, Het anhydride ,7-methanoisobenzofuran-1
CAS Number115-27-5
PubChem Substance ID87570765
EC Number204-077-3
Beilstein Registry Number92693
MDL NumberMFCD00080438
Reaxys-RN92693
Merck Number2086
Chemical Name Translation1,4,5,6,7,7-六氯-5-降冰片烯-2,3-二甲酸酐
InChIKeyFLBJFXNAEMSXGL-UHFFFAOYSA-N
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分类

  • {SNA} Alicyclic/Etch-Resistant Monomers, Curing Agents for Epoxides, Lithography Monomers, Micro/NanoElectronics, Polymer Additives, Polymer Science, Self Assembly & Contact Printing, 材料科学
  • {SA} Alicyclic/Etch-Resistant Monomers, Crosslinking Agents and Additives for Epoxides, Lithography Monomers, Materials Science,

相关文献及参考

  • Aldrich MSDS 1 , 1014:D / Corp MSDS 1 (1), 1835:B / FT-IR 2 (1), 1217:D / FT-IR 1 (1), 720:A / FT-NMR 1 (1), 1182:C / IR-Spectra (3), 420:G / IR-Spectra (2), 372:B / RegBook 1 (1), 839:C / Structure Index 1 , 130:A:5
  • Beil. 17 ,IV,6070
  • Merck 14 ,2086

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T Xi,N,T T;N Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSRB9080000
Precautionary statements
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P305+P351+P338+P337+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P302+P352+P333+P313+P362+P364
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
Signal word
Storage condition Moisture Sensitive 0-10 储存温度2-8℃ 0-10°C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S25 Avoid contact with eyes 避免眼睛接触；
Risk Statements
  • R45 May cause cancer 可能致癌
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R51/53
  • R48/20/21/22
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R52/53
UN Number 1759 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 26(4),49,1982

其他信息

  • 灭火剂:水,二氧化碳, 泡沫, 干粉
  • 可燃性危险特性:热分解排出有毒氯化物烟雾
  • 类别:有毒物质
  • 氯桥酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0349 氯桥酸酐 Het Anhydride 500G 578元 2014/06/02 H0349 氯桥酸酐 Het Anhydride 25G 150元 2010/06/21 146950010 氯桥酸酐 1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic anhydride 96% 1 KG 1084元
  • Acros Organics:氯茵酸酐 1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dicarboxylic anhydride, 96%(115-27-5)
  • 图谱信息:氯桥酸酐(115-27-5)核磁图( 1 HNMR) 氯桥酸酐(115-27-5)核磁图( 13 CNMR) 氯桥酸酐(115-27-5)红外图谱(IR3) 氯桥酸酐(115-27-5)红外图谱(IR1) 氯桥酸酐(115-27-5)红外图谱(IR2)
  • Sigma Aldrich:115-27-5(sigmaaldrich)
  • 急性毒性:口服-大鼠 LD50: 2300 毫克/公斤; 口服-小鼠 LD50: 2400 毫克/公斤
  • 毒性分级:中毒
  • 方法一:由六氯环戊二烯与顺酐反应而得。将六氯环戊二烯与顺酐按1：1.1的摩尔比混合在溶剂氯苯中，在140-145℃反应7-8h后，将反应产物加入水中水解，在70℃时水解得到的氯桥酸成为油状液体，加热到96-97℃时与水混溶，冷却后成为含一结晶水的氯桥酸（Het acid[115-28-6]）。若反应产物用热水及稀乙酸进行结晶，一水合物经100-105℃干燥，即得氯桥酸酐。
  • 上游原料:六氯环戊二烯 --> 氯菌酸
  • MOL 文件:115-27-5.mol
  • Alfa Aesar:<=3% Chlorendic anhydride, 96%, may cont. up to 3% chlorendic acid(115-27-5)" href="http://www.alfa.com/zh/GP100w.pgm?DSSTK=L07349&CAS;=115-27-5">氯菌酸酐,96%,氯菌酸<=3% Chlorendic anhydride, 96%, may cont. up to 3% chlorendic acid(115-27-5)
  • 蒸气密度:13 (vs air)
  • 刺激数据:眼睛-兔 100 毫克 重度
  • 储运特性:库房低温通风干燥
  • 用途二:氯桥酸酐和氯桥酸都是反应型阻燃剂，适用于不饱和聚酯、聚氨酯和环氧树脂，也用作环氧树脂固化剂。由该品固化的环氧树脂制品的热变形温度约180℃，耐药性好，氯桥酸也作为染料中间体和杀虫剂。也用作织物的阻燃剂。
  • TCI Shanghai:氯桥酸酐 Het Anhydride,>;95.0%(T)(115-27-5)
  • 用途一:用作环氧树脂和聚氨酯的反应型阻燃剂
  • 敏感性:Moisture Sensitive

系列性分类

  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymer Additives - Polymer Science
  4. Crosslinking Agents and Additives for Epoxides - Polymer Additives
  1. Functional Group 官能团索引
  2. carboxylic acid anhydride

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