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• 试剂商城
• 直接询价

分类

• {SNA} NMR Reference Standards,
• Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
• {SNA} Alphabetical Listings, NMR Reference Standards, NMR Solvents and Reagents, Stable Isotopes, T
• {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
• {SNA} Alphabetical Index of Analytical Standards, Alphabetical Listings, Analytical Standards, Analytical/Chromatography, NMR, NMR Reference Standards, Spectroscopy, Stable Isotopes, T,
• {SNA} Alphabetical Index of Analytical Standards, Alphabetical Listings, Analytical Standards, Analytical/Chromatography, NMR Reference Standards, NMR Solvents and

产品应用

• 气相色谱固定液(最高使用温度175℃，溶剂为乙醚)，选择性与聚乙二醇相似，能选择性保留醇类化合物。

相关文献及参考

• Kang, C., et al.: J. Appl. Entomol., 130, 377 (2006),
• Short: III/35D2
• Ay, R., et al.: J. Pest. Sci., 78, 139 (2005),
• Merck:14,9742 Beilstein:6,179
• Short: III/20a
• Stumpf, N., et al.: J. Econ. Entomol., 94, 1577 (2001),
• Merck:14,9742
• Reaction with a secondary alcohol in the presence of a base, e.g. quinoline, gives the diphenyl phosphate ester of the alcohol. This undergoes thermal elimination in sulfolane or NMP to provide the corresponding alkene. The method has clear advantages in terms of yield and toxicity over analogous routes to alkenes, such as the Chugaev xanthate thermolysis or heating the alcohol in HMPA: Synthesis, 1300 (1995). See also Diphenyl­ phosphorochloridate, A13546.

安全信息

GHS Symbol

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Primate - monkey
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
   (BEIs) booklet issues by American Conference of Governmental Industrial
   Hygienists (ACGIH), Cincinnati, OH, 1996  Volume(issue)/page/year:
   4,420,1980

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : >4 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEHLAU Archives of Environmental Health.  (Heldref Pub., 4000 Albemarle St.,
   NW, Washington, DC 20016)  V.1-    1960-  Volume(issue)/page/year: 1,33,1960

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3500 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - ataxia
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 7,585,1957

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NIHBAZ National Institutes of Health, Bulletin.  (Bethesda, MD)
   Volume(issue)/page/year: 160,1,1932

{h

TYPE OF TEST

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED

{hazard_co

其他信息

• 用途二:用作硝化纤维、醋酸纤维和聚氯乙烯等塑料的增塑剂
• 下游产品:聚氯乙烯 --> 环氧煤沥青防腐涂料 --> 硝基漆
• 图谱信息:磷酸三苯酯(115-86-6)红外图谱(IR2) 磷酸三苯酯(115-86-6)红外图谱(IR1) 磷酸三苯酯(115-86-6)红外图谱(IR3) 磷酸三苯酯(115-86-6)核磁图( 13 CNMR) 磷酸三苯酯(115-86-6)核磁图( 1 HNMR) 磷酸三苯酯(115-86-6)质谱(MS) 磷酸三苯酯(115-86-6)Raman光谱
• 用途四:气相色谱固定液(最高使用温度175℃，溶剂为乙醚)，选择性与聚乙二醇相似，能选择性保留醇类化合物。
• 上游原料:氯 --> 三氯化磷 --> 苯酚 --> 正辛醇 --> 亚磷酸三苯酯 --> 2-苯基-1-丙烯
• 储运特性:库房低温, 通风, 干燥; 与氧化剂分开存放
• Alfa Aesar:磷酸三苯基酯,98% Triphenyl phosphate, 98%(115-86-6)
• TCI Shanghai:磷酸三苯酯 Triphenyl Phosphate,>;99.0%(GC)(115-86-6)
• 毒性分级:中毒
• MSDS 信息:磷酸三苯酯(115-86-6).msds
• 灭火剂:雾状水、泡沫、二氧化碳、干粉、砂土。
• Acros Organics:磷酸三苯酯 Triphenyl phosphate, 99+%(115-86-6)
• 类别:有毒物质
• 蒸气压:1.3 mm Hg ( 200 °C)
• 海关编码:29190010
• 外观性质:白色、无臭结晶粉末, 微有潮解性。
• 磷酸三苯酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30187427 磷酸三苯酯 250g 50元 2011/04/16 P0272 磷酸三苯酯 Triphenyl Phosphate 25G 117元 2011/04/16 P0272 磷酸三苯酯 Triphenyl Phosphate 500G 240元
• 检测方法:HPLC,NMR
• 用途一:用于增加塑料加工成型时的可塑性和流动性能
• 微具芳香气味，不可燃，微有潮解性，本产品不溶于水(＜0.002%)，微溶于乙醇，能与醚、苯、丙酮、氯仿等有机溶剂混溶，对紫外线有吸收作用
• Sigma Aldrich:115-86-6(sigmaaldrich)
• 急性毒性:口服-大鼠 LD50: 3500 毫克/公斤; 口服-小鼠 LD50: 1320 毫克/公斤
• 可燃性危险特性:热, 明火, 氧化剂燃烧; 火场排出磷氧化物烟雾
• 职业标准:TWA 3 毫克/立方米; STEL 6 毫克/立方米
• MOL 文件:115-86-6.mol
• 用途三:用作气相色谱固定液、纤维素和塑料的增塑剂及赛璐璐中的樟脑不燃性取代物