CAS 119-93-7 MFCD00014773-4,4’-Diamino-3,3’-Dimethylbiphenyl 4,4’-二氨基-3,3’-二甲基联苯 -LabNovo

4,4’-Diamino-3,3’-Dimethylbiphenyl 4,4’-二氨基-3,3’-二甲基联苯

CAS 119-93-7 MFCD00014773

化学结构图

SMILES: Cc1cc(-c2ccc(N)c(C)c2)ccc1N

化学属性

Mol. Formula	C14H16N2
Mol. Weight	212
Melting Point	128-131
Refractive index	n20/D 1.341
Flash Point	244°(471°F)
TSCA	Yes
Boiling Point	300
Density	1.106
Stability	对光和空气敏感
Solubility	2% HCl: 10 mg/mL, clear
Appearance	powder (may contain lumps)

别名和识别编码

Chemical Name	4,4’-Diamino-3,3’-Dimethylbiphenyl
Synonym	3,3' 3,3'-Dimethyl-4,4'-biphenyldiamine 3,3'-dimethyl-biphenyl-4,4'-diamine 3,3'-Dimethylbiphenyl-4,4'-diamine 3,3'-二甲基联苯胺, 4,4'-二氨基-3,3'-二甲基联苯 3,3-Dimethylbenzidine 3，3，-二甲基联苯胺 4'-Amino-3,3'-dimethyl[1,1'-biphenyl]-4-ylamine 4,4'-BIANISIDINE 4,4'-Bi-o-toluidine 4,4′-Bianisidine o,o'-Tolidine o-To Bianisidine C.I. Azoic Diazo Component 113 Ellms-Hauser 溶液 O-TOLIDINE ORTHO-TOLIDINE REAGENT azoic diazo component 113 o-Tolidin o-Tolidine; 3,3'-Dimethylbiphenyl-4,4'-diamine; C.I. 37230; Azoic diazo component 113; DMB; Fast Dark Blue Base R {} {} {} {} { {} {} {} {} {Ch {} {} {} {} {Chemi {} {} {} {} {Chemica {} {} {} {} {hazard_co 托力 {
MDL Number	MFCD00014773
CAS Number	119-93-7
EC Number	204-358-0
Beilstein Registry Number	2210640
PubChem Substance ID	87576235
Merck Number	9514
Chemical Name Translation	4,4’-二氨基-3,3’-二甲基联苯
Reaxys-RN	2210640
Wiswesser Line Notation	ZR B1 DR DZ C1
LabNetwork Molecule ID	LN00193641

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

金、铈、游离氯的光度测定。测定硝酸盐、锰、亚硝酸盐、铬盐、铜盐、钴、汞和空气中的氰离子。
分析标准品是测定金和游离氯的灵敏比色光敏。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H302 Harmful if swallowed 吞食有害
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H350 May cause cancer 可能致癌
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSDD1225000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P312+P330
P305+P351+P338
P308+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Packing GroupIII

UN Number 3077 UN 3082 9/PG 3 UN3077

Risk Statements

R22 Harmful if swallowed 吞咽有害
R34 Causes burns 会导致灼伤
R37 Irritating to respiratory system 刺激呼吸道
R45 May cause cancer 可能致癌
R51/53
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险

Hazard Codes 9 T T,N

Storage condition 密封避光保存。密封避光保存。充氩操作

Hazard Class9

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4500 mg/kg/27D-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   28,924,1968

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5040 mg/kg/56W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Sense Organs and Special Senses (Ear) - effect, not otherwise specified
   Endocrine - tumors
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 9(7),18,1965

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Implant
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5040 mg/kg/1Y-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
   Skin and Appendages - tumors
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   45,283,1970

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1650 mg/kg/33W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie.  (Leipzig,
   Ger. Dem. Rep.)  V.1-109, 1873-1925.  For publisher information, see NSAPCC.
    Volume(issue)/page/year: 58,167,1907

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 125 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,64,1954

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 1 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   38,2621,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 4 ug/plate
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 26 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   12(Suppl 13),37,1988

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 5 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - rat Embryo
DOSE/DURATION           : 5 mg/L
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   51,799,1973

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 450 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issu

Restrict 危险品

其他信息

NIST化学物质信息:[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethyl-(119-93-7)
color:light brown
用途:主要用于合成色酚AS-G，也作冰染染料的显色基、偶氮染料的中间体和树脂固化剂
MOL 文件:119-93-7.mol
F:8
RTECS号:DD1225000
外观性质:白色至微红色有闪光的片状结晶。
色指数:37230
图谱信息:4,4'-二氨基-3,3'-二甲基联苯(119-93-7)核磁图( 13 CNMR) 4,4'-二氨基-3,3'-二甲基联苯(119-93-7)质谱(MS) 4,4'-二氨基-3,3'-二甲基联苯(119-93-7)红外图谱(IR3) 4,4'-二氨基-3,3'-二甲基联苯(119-93-7)核磁图( 1 HNMR) 4,4'-二氨基-3,3'-二甲基联苯(119-93-7)红外图谱(IR2) 4,4'-二氨基-3,3'-二甲基联苯(119-93-7)红外图谱(IR1)
有苯胺样气味。见光或久置色变深。溶于醇、醚和稀酸，微溶于水。中等毒，半数致死量（大鼠，经口）404mg/kg。有致癌可能性。有刺激性。
毒害物质数据:119-93-7(Hazardous Substances Data)
EPA化学物质信息:[1,1'-Biphenyl]- 4,4'-diamine, 3,3'-dimethyl-(119-93-7)
PackingGroup:III
HazardClass:6.1(b)
4,4'-二氨基-3,3'-二甲基联苯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80130614 邻联甲苯胺;二氨基二甲基联苯;3,3′-二甲基联苯胺;邻甲联苯胺;4,4′-二氨基-3,3′-二甲基联苯 25g 47元 2011/08/23 K8958002 邻联甲苯胺;二氨基二甲基联苯;3,3′-二甲基联苯胺;邻甲联苯胺;4,4′-二氨基-3,3′-二甲基联苯 100g 1517元 2011/08/23 80130680 邻联甲苯胺;二氨基二甲基联苯;3,3′-二甲基联苯胺;邻甲联苯胺;4,4′-二氨基-3,3′-二甲基联苯 25g 100元

4,4’-Diamino-3,3’-Dimethylbiphenyl 4,4’-二氨基-3,3’-二甲基联苯

CAS 119-93-7 MFCD00014773

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