Chloro(1,5-Cyclooctadiene)Rhodium(I) Dimer (1,5-环辛二烯)氯铑(I)二聚体

CAS 12092-47-6 MFCD00012415

化学结构图

12092-47-6
SMILES: C1=CCCC=CCC1.C1=CCCC=CCC1.Cl[Rh].Cl[Rh]

化学属性

Mol. FormulaC16H24Cl2Rh2
Mol. Weight493.08
Melting Point243 °C (dec.)(lit.)
SolubilitySparingly soluble in most common solvents
TSCAYes
Density1.422
Stability易吸潮
Appearance yellow to orange xtl.

别名和识别编码

Chemical NameChloro(1,5-Cyclooctadiene)Rhodium(I) Dimer
Synonym 氯(1,5-环辛二烯)铑二聚 Bis(1,5-cyclooctadiene)dirhodium(I) dichloride 5-环辛二烯)铑(Ⅰ) 1,5-环辛二烯氯铑(I)二聚体 (1,5-环辛二烯)氯铑(I)二聚体 环辛二烯络氯化铑 1,5-环辛二烯氯化铑(I)二聚体 氯(1,5-环辛二烯)铑(I)二聚体 氯化铑(I) 1,5-环辛二烯络合物二聚体 1,5-环辛二烯氯铑(I)二聚体 [Rh(COD)Cl]2 二聚氯代(1,5-环辛二烯)铑(I) 双(1,5-环辛二烯氯化铑) 环辛二烯络氯化铑 Bis(1,5-cyclooctadienerhodium chloride) 二聚氯代(1,5-环辛二烯)铑(Ⅰ) 双(1,5-环辛二烯氯化铑) 5-环辛二烯)氯铑(I)二聚体 氯(1 (1 [Rh(COD)Cl]2 5-环辛二烯)铑二聚，二聚氯代(1 二聚氯代(1,5-环辛二烯)铑(I)
MDL NumberMFCD00012415
EC Number235-157-6
PubChem Substance ID87563994
CAS Number12092-47-6
Beilstein Registry Number2384789
Chemical Name Translation(1,5-环辛二烯)氯铑(I)二聚体
Reaxys-RN14860700
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分类

  • {SNA} 12 Principles Aligned Products, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Greener Alternative Products, Rhodium
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium
  • {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Rhodium
  • {SNA} 12 Principles Aligned Products, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Greener Alternative Products, Rhodium Catalysts

产品应用

  • 1,3-二烯和激活的烃反应的催化剂及制备手性复合物。耦合反应；不对称氢化反应； 硼氢化反应。

相关文献及参考

  • Catalyzes the dehydrogenative coupling reaction of styrenes with Pinacolborane, L17558 to give the corresponding vinylboronates: Tetrahedron Lett., 40, 2585 (1999); Bull. Chem. Soc. Jpn., 75, 825 (2002). The complex has also been found to promote the atmospheric pressure carbonylation of benzylic halides to give good yields of phenylacetic acids: Tetrahedron Lett., 41, 7601 (2000).
  • Homogeneous catalyst and catalyst precursor. For use in the preparation of a chiral BINAP alkene isomerization catalyst, see: Org. Synth. Coll., 8, 183 (1993).
  • Miyaura has reported the Rh-catalyzed conjugate addition of arylboronic acids to ɑß-unsaturated carbonyl compounds in a single aqueous phase: Chem. Lett., 722 (2001):

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition Air Sensitive & Hygroscopic 易吸潮，密闭干燥冷藏。
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi

其他信息

  • 易吸潮。微溶于大多数普通溶剂。不溶于水。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Yttrium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhenium
  1. Catalysts
  2. Rhodium

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