1,1-Bis(diphenylphosphino)ferrocene 1,1'-双(二苯基膦)二茂铁

CAS 12150-46-8 MFCD00001422

化学结构图

12150-46-8
SMILES: [CH]1[CH][CH][C](P(c2ccccc2)c2ccccc2)[CH]1.[CH]1[CH][CH][C](P(c2ccccc2)c2ccccc2)[CH]1.[Fe]

化学属性

Mol. FormulaC34H28FeP2
Mol. Weight554.39
Melting Point181-182 °C (dec.)(lit.)
TSCANo
Density1.527
Stability对湿度敏感
Appearance yellow to orange xtl.

别名和识别编码

Chemical Name1,1-Bis(diphenylphosphino)ferrocene
CAS Number12150-46-8
Alfabeta NameBISDIPHENYLPHOSPHINOFERROCENE 11()-,'
MDL NumberMFCD00001422
Synonym 1,1'-Bis(diphenylphosphino)ferrocene 1,1'-Bis-(diphenylphosphino)-ferrocen 1,1'-Ferrocenbis-(diphenylphosphin) 1,1'-Ferrocenebis(diphenylphosphine) 1,1'-bis(diphenylphosphino) ferrocene 1,1'-Ferrocendiylbis(diphenylphosphine) 1,1'-Ferrocenebis(diphenylphosphine); 1,1'-Ferrocenediyl-bis(diphenylphosphine) 1,1'-双(二苯基膦)二茂铁 1,1-Bis(diphenylphosphino)ferrocene 1,1′-Ferrocenediyl-bis(diphenylphosphine), 1,1′-Ferrocenebis(diphenylphosphine) 1,1′-二茂铁二基-双(二苯基膦) 1,1′-双(二苯基膦)二茂铁 dppf 1,1′-二茂铁二基-双(二苯基膦) dppf 1,1′-双(二苯基膦)二茂铁 Cyclopentadienyldiphenylphosphine Dppf dppf 双(二苯基膦)二茂铁 双(二苯基膦)二茂铁;1,1′-二茂铁二基-双(二苯基膦) 锆离子载体 I
PubChem Substance ID87564906
EC Number430-420-3
Beilstein Registry Number2384789
Chemical Name Translation1,1'-双(二苯基膦)二茂铁
LabNetwork Molecule IDLN01358153
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分类

  • Aromatics
  • Catalyst
  • {SNA} Analytical/Chromatography, Ion Sensor Materials, Ionophores Potentiometric for ISE
  • {SNA} 12 Principles Alig
  • {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Phosphine Compounds, Polydentate Phosphine Ligands
  • Chelating Agents & Ligands
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands
  • {SNA} 12 Principles Aligned Products, Related Palladacycles, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Greener Alternative Products, Phosphine Compounds, Polydentate Phosphine Ligands

产品应用

  • 有机金属催化剂（配体）。通过钯-膦催化的 C-C 和 C-O 键顺序成键反应制备新型官能化呋喃衍生物。

相关文献及参考

  • Short: III/35D5
  • Nataro, C., et al.: J. Chem. Ed., 86, 1412 (2009),
  • Short: ELINCS
  • Hindered bidentate ligand used in, for example, the Ni-catalyzed Suzuki-type crossed coupling of arylboronic acids with aryl mesylates to give biaryls: J. Org. Chem., 60, 1060, 1066 (1995), and of thiophenolates with aryl mesylates to give unsymmetrical diaryl sulfides: J. Org. Chem., 60, 6895 (1995).

安全信息

Warnings IRRITANT, KEEP COLD
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 密封保存。 Air Sensitive
Signal word Danger Warning
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P313 Get medical advice/attention. 获取医疗咨询/就医
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Codes 6.1 T
Hazard statements
  • H302+H312+H332
Packing GroupIII
UN Number 3467

其他信息

  • 在空气中稳定。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Ion Sensor Materials
  3. Ionophores Potentiometric for ISE - Ion Sensor Materials
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Karl Fischer Titration HYDRANAL® Reagents for Water Determination
  5. Volumetric Reagents for Volumetric Karl Fischer Titration
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Polydentate Phosphine Ligands 多齿膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Polydentate Phosphine Ligands 多齿膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metallocenes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Phosphorus Precursors
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Iron
  1. Ligands
  2. Iron
  1. Ligands
  2. 96-1650 Phosphine Ligand Kit for Palladium-Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond Formation
  1. Phosphine
  2. 96-1650 Phosphine Ligand Kit for Palladium-Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond Formation