Tris(pentafluorophenyl)phosphine 三(五氟苯基)膦

CAS 1259-35-4 MFCD00079654

化学结构图

1259-35-4
SMILES: Fc1c(F)c(F)c(P(c2c(F)c(F)c(F)c(F)c2F)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F

化学属性

Mol. FormulaC18F15P
Mol. Weight532.15
Melting Point108-110
TSCANo
Density1.11
Appearance white pwdr.
Boiling Point343.4±42.0 °C at 760 mmHg

别名和识别编码

Chemical Nametris(2,3,4,5,6-pentafluorophenyl)phosphane
MDL NumberMFCD00079654
CAS Number1259-35-4
Beilstein Registry Number773243
EC Number215-021-2
Synonym Tris(pentafluorophenyl)phosphine {LY} Tris(pentafluorophenyl)phosphine phosphine, tris(pentafluorophenyl)- tris(pentafluorophenyl)phosphine {} {LY} Tris(pentafluorophenyl)phosphine {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {} {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {} {} {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {} {} {} {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {} {} {} {} {} {} {PubChem} TPFPP {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(pentafluorophenyl)phosphine {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID102076
Reaxys-RN773243
Chemical Name Translation三(五氟苯基)膦
LabNetwork Molecule IDLN00223152
InChIKeyFQLSDFNKTNBQLC-UHFFFAOYSA-N
InChIInChI=1S/C18F15P/c19-1-4(22)10(28)16(11(29)5(1)23)34(17-12(30)6(24)2(20)7(25)13(17)31)18-14(32)8(26)3(21)9(27)15(18)33
Canonical SMILESFC1=C(F)C(F)=C(F)C(F)=C1P(C2=C(F)C(F)=C(F)C(F)=C2F)C3=C(F)C(F)=C(F)C(F)=C3F
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands

相关文献及参考

  • In a study of Pd-catalyzed coupling reactions in supercritical CO2, this ligand was among the best tried for the Heck reaction, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)­phenyl­]phosphine, L06941.
  • Standard for mass spectrometry.

安全信息

GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Store at room temperature {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:1259-35-4(sigmaaldrich)
  • Alfa Aesar:三(五氟苯基)膦,95% Tris(pentafluorophenyl)phosphine, 97%(1259-35-4)
  • 三(五氟苯基)膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2484 三(五氟苯基)膦 Tris(pentafluorophenyl)phosphine 5G 1550元 2014/06/02 T2484 三(五氟苯基)膦 Tris(pentafluorophenyl)phosphine 1G 521元 2010/06/21 313160010 三(五氟苯基)膦 Tris(pentafluorophenyl)phosphine 97% 1 GR 532元
  • TCI Shanghai:三(五氟苯基)膦 Tris(pentafluorophenyl)phosphine,>;95.0%(GC)(1259-35-4)
  • Hazard Note:Irritant
  • Acros Organics:三(五氟苯基)膦 Tris(pentafluorophenyl)phosphine, 97%(1259-35-4)
  • F:10
  • MOL 文件:1259-35-4.mol

系列性分类


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