1,4-Diaminoanthraquinone 1,4-二氨基蒽醌

CAS 128-95-0 MFCD00001224

化学结构图

128-95-0
SMILES: Nc1ccc(N)c2c1C(=O)c1ccccc1C2=O

化学属性

Mol. FormulaC14H10N2O2
Mol. Weight238.24
Melting Point265-269 °C
Density1.422
TSCAYes
Flash Point340 °C
Appearance 1,4-二氨基蒽醌(128-95-0)为深紫色针状结晶。熔点268℃。溶于乙醇、苯和硝基苯，微溶于水和热乙酸。
Solubility溶于苯、吡啶、硝基苯、苯胺，稍溶于热醋酸、乙醇。
Boiling Point380.84 °C at 760 mmHg

别名和识别编码

Chemical Name1,4-Diaminoanthraquinone
CAS Number128-95-0
Synonym 1,4-Diaminoanthraquinone {LY} 1,4-Diaminoanthraquinone 1,4-diaminoanthraquinone {} {LY} 1,4-Diaminoanthraquinone {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {PubChem} 1,4-DAA {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Diaminoanthraquinone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00001224
Beilstein Registry Number14(4)458
EC Number204-922-6
Reaxys-RN2216556
PubChem Substance ID31420
Chemical Name Translation1,4-二氨基蒽醌
Wiswesser Line NotationL C666 BV IVJ DZ GZ
InChIInChI=1S/C14H10N2O2/c15-9-5-6-10(16)12-11(9)13(17)7-3-1-2-4-8(7)14(12)18/h1-6H,15-16H2
LabNetwork Molecule IDLN00223623
Canonical SMILESC1=CC=C2C(=C1)C(=O)C3=C(C=CC(=C3C2=O)N)N
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 14ring; ketone; 1fragment
  • Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {SNA} Amine Monomers, Materials Science, Monomers, Polymer Science, Primary Amines
  • {SNA} Amine Monomers, Monomers, Polymer Science, Primary Amines, 材料科学

产品应用

  • An anthraquinone derivative that is a potent and selective protein kinase CK1 delta inhibitor. Studies suggest that it has potential solar cell applications. Used in studies as a potential competitiv

相关文献及参考

  • Cozza, G. et al.: Bioorg. Med. Chem. Lett., 18, 5672 (2008); Brovelli, F. et al.: Polym. Bull., 58, 521 (2007); Brinkworth, R.I. et al.: Biochim. Biophys. Acta, Prot. Struct. Mol. Enzymol., 1253, 5 (1
  • Beil. 14 ,IV,458
  • FT-IR 1 (1), 90:C / RegBook 1 (2), 1691:L / Structure Index 1 , 268:D:7
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSCB6300000
WGK Germany2
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P301+P316
  • P301+P317
  • P302+P350
  • P302+P352
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P333+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5790 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku,"
   Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu
   Praha, Czechoslovakia, 1972  Volume(issue)/page/year: -,121,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 21(12),27,1977

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 12800 ug/L
REFERENCE :
   HEREAY Hereditas (Lund, Sweden).  (Gjoerloffsgatan 121, S-261 34 Landskrona,
   Sweden)  V.1-    1947-  Volume(issue)/page/year: 99,209,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,203,1976

Storage condition

其他信息

  • 用途三:用于涤纶的染色
  • 方法一:由对苯二酚与苯酐缩合得1,4-二羟基蒽醌，然后氨化得1,4-二氨基蒽醌隐色体，再以发烟硫酸氧化而得。原料消耗定额：苯酐2131kg/t、对苯二酚887kg/t、氨水（20%）10788kg/t、发烟硫酸3580kg/t。
  • TCI Shanghai:1,4-二氨基蒽醌 1,4-Diaminoanthraquinone,>;97.0%(N)(128-95-0)
  • 用途一:用作合成染料的中间体
  • 1,4-二氨基蒽醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0075 1,4-二氨基蒽醌 1,4-Diaminoanthraquinone 25G 967元 2014/06/02 D0075 1,4-二氨基蒽醌 1,4-Diaminoanthraquinone 1G 176元 2014/06/02 D3539 1,4-二氨基蒽醌 1,4-Diaminoanthraquinone 500G 1770元
  • Alfa Aesar:1,4-二氨基蒽醌,tech.90% 1,4-Diaminoanthraquinone, tech. 90%(128-95-0)
  • MOL 文件:128-95-0.mol
  • 用途二:用作染料中间体，广泛用于还原灰BG、分散翠蓝HBF及酸性染料等
  • 下游产品:兰雪醌 --> 还原黑 27 --> 分散紫 H-FRL --> 还原棕 1 --> 分散紫 26 --> 还原棕BR --> 活性分散蓝 R --> 分散紫 28 --> 分散蓝 60 --> 碱性蓝 47
  • 上游原料:氢氧化钠 --> 碳酸氢钠 --> 发烟硫酸 --> 硫磺 --> 1,4-苯二酚 --> 4-硝基苯胺 --> 1,4-二羟基蒽醌 --> 2,4-二氨基甲苯
  • 用途四:蒽醌还原染料、分散染料、酸性染料和中间体。本身为分散染料紫。
  • Sigma Aldrich:128-95-0(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C13 to C14 - Ketones
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Amine Monomers - Monomers
  5. Primary Amines - Amine Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Anthraquinones

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