4-Methoxyphenylmagnesium Bromide 4-甲氧基苯基溴化镁

CAS 13139-86-1 MFCD00013515

化学结构图

13139-86-1
SMILES: COC1C=CC(=CC=1)[Mg]Br

化学属性

Mol. FormulaC7H7BrMgO
Mol. Weight211
Density0.955
Flash Point-20°(-4°F)
TSCANo
Boiling Point65-67 °C
Solubility剧烈反应
Stability空气及湿度敏感;干的残留物是爆炸性的

别名和识别编码

Chemical Name4-Methoxyphenylmagnesium Bromide
MDL NumberMFCD00013515
Synonym 4-METHOXYPHENYLMAGNESIUM BROMIDE p-Anisylbromomagnesium 4-Methoxyphenylmagnesium bromide, 1M solution in THF 4-Methoxyphenylbromomagnesium 4-Methoxyphenylmagnesium bromide solution 4-茴香溴化镁 4-Anisylmagnesium bromide 4-甲氧基 苯基溴化镁,0.5M IN THF 4-Methoxyphenylmagnesium bromide1M solution in THFAcroSeal§3 4-甲氧基苯基溴化镁 4-Methoxyphenylmagnesium Bromide 1.0 M In Tetrahydrofuran (4-Methoxyphenyl)bromomagnesium 4-甲氧基苯基溴化镁 溶液 4-METHOXYPHENYLMAGNESIUM BROMIDE, 0.5M S OLUTION IN TETRAHYDROFURAN p-Anisylmagnesium bromide 4-ANISYLMAGNESIUM BROMIDE 4-METHOXYPHENYLMAGNESIUM BROMIDE 0.5 M IN THF 4-anisylmagnesium bromide, 0.5m in thf P-ANISYLMAGNESIUM BROMIDE
CAS Number13139-86-1
PubChem Substance ID24870649
Chemical Name Translation4-甲氧基苯基溴化镁
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分类

  • {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

安全信息

Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S8 Keep container dry 保持容器干燥；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Packing GroupII
UN Number 2924 UN 2924 3/PG 2 UN2924
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
Storage condition Flammables + water-Freezer (-20°C)e area Air & Moisture Sensitive 密封充氩保存。
WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
GHS Symbol
Hazard Codes 3 F,C
Restrict 危险品

其他信息

  • 4-甲氧基苯基溴化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 377428000 4-甲氧基苯基溴化镁 4-Methoxyphenylmagnesium bromide , 1M solution in THF, AcroSeal® 800 ML 1715元 2010/06/21 377421000 4-甲氧基苯基溴化镁 4-Methoxyphenylmagnesium bromide , 1M solution in THF, AcroSeal® 100 ML 585元 2010/05/25 89435 4-Anisylmagnesium bromide, 0.5M in THF 0.25mole 2044元
  • 和水剧烈反应。
  • HazardClass:4.3
  • PackingGroup:II
  • 敏感性:Air & Moisture Sensitive
  • MOL 文件:13139-86-1.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Aryl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Aryl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkynyl

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