Dichloro [(R)-(+)-2,2’-Bis(Diphenylphosphino)-1,1’-Binaphathyl] Ruthenium(Ii) R-(+)-氯化钌BINAP
CAS 132071-87-5 MFCD01073794
化学结构图
SMILES:
化学属性
| Mol. Formula | C44H32Cl2P2Ru |
|---|---|
| Mol. Weight | 794.65 |
| Melting Point | >;300 °C |
| Appearance | orange pwdr. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | Dichloro [(R)-(+)-2,2’-Bis(Diphenylphosphino)-1,1’-Binaphathyl] Ruthenium(Ii) |
|---|---|
| Synonym | (S)-[2,2′-双(二苯基膦)-1,1′-联萘]二氯化钌 (R)-BINAP 二氯化钌络合物 (R)-[1,1′-联萘]-2,2′-二基双[二苯膦]钌络合物 [(R)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium (S)-BINAP 二氯化钌络合物 (S)-[1,1′-联萘]-2,2′-二基双[二苯膦]钌络合物 [(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium (R)-[2,2′-双(二苯基膦)-1,1′-联萘]二氯化钌 |
| MDL Number | MFCD01073794 |
| CAS Number | 132071-87-5 |
| Reaxys-RN | 15397757 |
| PubChem Substance ID | 329762304 |
| Chemical Name Translation | R-(+)-氯化钌BINAP |
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分类
- Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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