Furan-2-Boronic Acid 2-呋喃硼酸

CAS 13331-23-2 MFCD00799544

化学结构图

13331-23-2
SMILES: OB(O)c1ccco1

化学属性

Mol. FormulaC4H5BO3
Mol. Weight112
Melting Point112 °C (dec.)(lit.)
TSCANo
Density1.25
Stability对空气敏感

别名和识别编码

Chemical NameFuran-2-Boronic Acid
CAS Number13331-23-2
Alfabeta NameFURANBORONICACID 2--
MDL NumberMFCD00799544
Synonym 2-Furylboronic acid RARECHEM AH PB 0174 AKOS 90301 2-FURANYLBORONIC ACID (5-Furanyl)boronic acid 2-Furylboronic acid 呋喃-2-硼酸 2-FURYLBORONIC ACID 呋喃-2-硼酸 (5-Furanyl)boronic acid
PubChem Substance ID2734357
Reaxys-RN112370
EC Number000-000-0
Beilstein Registry Number112370
Chemical Name Translation2-呋喃硼酸
LabNetwork Molecule IDLN00004521
InChIInChI=1S/C4H5BO3/c6-5(7)4-2-1-3-8-4/h1-3,6-7H
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分类

  • {SNA} Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Heteroaryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • Beilstein: 18,IV,8398
  • Undergoes an asymmetric boronic acid Mannich reaction with aldehydes in the presence of the chiral template (S)-5-phenylmorpholine-2-one to give substituted furfurylamines with high diastereomeric excess: Chem. Commun., 1953 (1996); J. Chem. Soc., Perkin 1, 2982 (2000):

安全信息

Warnings IRRITANT, AIR SENSITIVE, KEEP COLD, STORED UNDER ARGON
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition Air Sensitive,储存温度2-8°C 0-6°C <;0 <0°C Air Sensitive 储存温度2-8°C
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P302+P352
  • P305+P351+P338+P337+P313
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Hazard Codes Xi

其他信息

  • MOL 文件:4347-32-4.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Furans 呋喃
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Heteroaryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Functional Group 官能团索引
  2. boronic acid

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