Chlorotripyrrolidinophosphonium hexafluorophosphate 氯代三吡咯烷基鏻六氟磷酸盐
CAS 133894-48-1 MFCD00210035
化学结构图
SMILES: F[P-](F)(F)(F)(F)F.Cl[P+](N1CCCC1)(N1CCCC1)N1CCCC1
化学属性
| Mol. Formula | C12H24ClF6N3P2 |
|---|---|
| Mol. Weight | 422 |
| Melting Point | 145° |
| TSCA | No |
| Boiling Point | 145-148 |
别名和识别编码
| Chemical Name | Chlorotripyrrolidinophosphonium hexafluorophosphate |
|---|---|
| Synonym | Pyclop |
| Beilstein Registry Number | 6842341 |
| PubChem Substance ID | 172089143 |
| CAS Number | 133894-48-1 |
| MDL Number | MFCD00210035 |
| Chemical Name Translation | 氯代三吡咯烷基鏻六氟磷酸盐 |
| Reaxys-RN | 6842341 |
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分类
- {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
相关文献及参考
- 1. Johan Svenson, et al Biochemistry 47 , 3777-3788, (2008) 摘要
- 2. Chanaz Salmi, et al Lett. Org. Chem. 2 , 628-633, (2005)
- 3. Frank Hoffmann, et al Phosphorus, Sulfur Silicon Relat. Elem. 178 , 299-309, (2003)
- 4. Mark Wehner, et al Eur. J. Org. Chem. 1 , 138-153, (2005)
- 5. Natsuhisa Oka, et al Tetrahedron 62 , 3667-3673, (2006)
- 6. P. Rzepecki, et al J. Org. Chem. 69 , 5168-5178, (2004)
- J. Coste et al. J. Org. Chem. 59 , 2437, (1994)
安全信息
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
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