Cupric Acetylacetonate 乙酰丙酮酸铜
CAS 13395-16-9 MFCD00000016
化学结构图
SMILES: CC(=O)/C=C(/C)\O[Cu]O/C(/C)=C\C(C)=O
化学属性
| Mol. Formula | C10H14CuO4 |
|---|---|
| Mol. Weight | 262 |
| Density | 1.422 |
| Melting Point | 284-288 |
| TSCA | Yes |
| Boiling Point | 160°/10mm |
| Solubility | 0.2 G/L (20 ºC) |
| Stability | 易吸潮 |
别名和识别编码
| Chemical Name | Cupric Acetylacetonate |
|---|---|
| CAS Number | 13395-16-9 |
| EC Number | 236-477-9 |
| Beilstein Registry Number | 4157957 |
| MDL Number | MFCD00000016 |
| PubChem Substance ID | 87565513 |
| Synonym | Kupfer(II)acetylacetonat Kupfer-bis-acetylaceton { Copper, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)- 2,4-戊二酮铜(II) Copper acetylacetonate Copper bis(acetylacetone) Nacem Copper Cupric bis(2,4-pentanedionate) Copper(II) bis(acetylacetonate) Bis-(acetylacetonato)-kupfer(II) 乙酰丙酮酸铜(II) Copper(II) acetylacetonate Cupric acetylacetonate Cu Acetylacetonate 乙酰丙酮酸铜 CD 9 2,4-戊二酮 铜(II) 衍生物 Copper bis(acetylacetonate) Cuprous bis(acetylacetonate) 双(2,4-戊二酮酸)铜(II);乙酰丙酮酸铜;乙酰丙酮酸铜(II);二乙酰丙酮铜;双(乙酰内酮)铜(Ⅱ);2,4-戊二酮銅(II) Bis(2,4-pentanedionato)copper Bis[2,4-pentanedionato]copper(II) |
| Chemical Name Translation | 乙酰丙酮酸铜 |
| Wiswesser Line Notation | 1VYV1&-CU-YV1&V1 |
| LabNetwork Molecule ID | LN02135064 |
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分类
- Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
- {uni_hamburg} no charge; ketone; 3fragments; ionic
- {SNA} Copper, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper,
产品应用
- 用作树脂交联剂和固化促进剂；橡胶添加剂；燃料油添加剂，可提高润滑性和燃烧性，但不能阻止碳沉积；用作有机合成催化剂。
相关文献及参考
- In catalytic amounts promotes the selective O-benzylation of primary alcohols with benzyl chloride, in the presence of secondary alcohols or phenols: Tetrahedron Lett., 44, 8483 (2003). For a brief feature on uses of the reagent in synthesis, see: Synlett, 2859 (2005).
- The most effective of a number of metal chelates studied in enabling the reduction of aromatic nitro-compounds by sodium borohydride: J. Chem. Soc., Perkin 1, 2409 (1979).
- Catalyst for the carbenoid reaction of diazoacetate esters with silyl enol ethers to give siloxycyclopropanes: Liebigs Ann. Chem., 512 (1984); Org. Synth. Coll., 9, 573 (1998).
- Short: III/20b
- Promotes the coupling of organozinc reagents with allylic halides to give , δ-unsaturated esters: Tetrahedron Lett., 24, 2749 (1983).
- Short: III/10a
- Beilstein: 1,781
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P304+P340+P312
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P305+P351+P338
- P332+P313
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P405 Store locked up. 上锁保管。
- P305+P351+P338+P337+P313
- P301+P312+P330
- P308+P313
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P302+P350
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P302+P352+P312+P362+P364
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302+H312+H332
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 19 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CHTHBK Chemotherapy (Basel). (S. Karger Pub., Inc., 79 Fifth Ave., New York, NY 10003) V.13- 1968- Volume(issue)/page/year: 16,371,1971
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 10 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00604
其他信息
- 易溶于氯仿，溶于苯和四氯化碳。溶解度:0.2 g/L水 (20°C)， 0.09 g/100g 醇 (20°C)，0.07 g/100g 苯 (20°C)。
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