(S,S)-(+)-N,N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine (S,S)-(+)-N,N’-双(3,5-二叔丁基邻羟亚苄基)-1,2-环己二胺

CAS 135616-36-3 MFCD00191801

化学结构图

135616-36-3
SMILES: CC(C)(C)C1=CC(=C(O)C(/C=N/[C@H]2CCCC[C@@H]2/N=C/C2C=C(C=C(C=2O)C(C)(C)C)C(C)(C)C)=C1)C(C)(C)C

化学属性

Mol. Formula[[(CH3)3C]2C6H2-2-(OH)CH=N]2C6H10
Mol. Weight546.83
Melting Point203-206 °C(lit.)
Appearance yellow pwdr.

别名和识别编码

Chemical Name(S,S)-(+)-N,N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine
Synonym (S,S)-(+)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺 (S,S)-Jacobsen 配体
Beilstein Registry Number5464823
PubChem Substance ID24865245
CAS Number135616-36-3
MDL NumberMFCD00191801
Chemical Name Translation(S,S)-(+)-N,N’-双(3,5-二叔丁基邻羟亚苄基)-1,2-环己二胺
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分类

  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SALENs
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SALENs

相关文献及参考

  • 1. Jacobsen, E.N. et al. J. Am. Chem. Soc. 113 , 7063, (1991)
  • 2. Deng, L. Jacobsen, E.N. J. Org. Chem. 57 , 4320, (1992)
  • 3. Chang, S. et al. J. Am. Chem. Soc. 58 , 6939, (1993)
  • FT-IR 2 (3), 4056:C / Structure Index 1 , 429:C:5

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SALENs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SALENs - Privileged Ligands and Complexes
  1. Jacobsen Ligand
  2. Nitrogen
  1. Ligands
  2. Nitrogen

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