Tri-t-Butylphosphine 三叔丁基膦溶液

CAS 13716-12-6 MFCD00015006

化学结构图

13716-12-6
SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C

化学属性

Mol. Formula[(CH3)3C]3P
Mol. Weight202.32
Boiling Point102-103 °C/13 mmHg(lit.)
Density0.861
Melting Point30-35 °C(lit.)
Flash Point-16°(-3°F)
TSCANo
Solubility不溶
Stability对空气敏感，对湿度敏感
Appearance colorless liq. colorless liq. to white solid
pH:A

别名和识别编码

Chemical NameTri-t-Butylphosphine
Synonym tris(1,1-dimethylethyl)phosphine Tri-tert-butylphosphine P(t-Bu)3 三特丁基膦 Tri-t-butylphosphine Tri-tert.-butylphosphin 三叔丁基膦 Tris(1,1-dimethylethyl)phosphine
PubChem Substance ID24860444
EC Number237-266-4
Beilstein Registry Number1738613
MDL NumberMFCD00015006
CAS Number13716-12-6
Chemical Name Translation三叔丁基膦溶液
InChIKeyBWHDROKFUHTORW-UHFFFAOYSA-N
LabNetwork Molecule IDLN00155764
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分类

  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/25D
  • Merck: 14,9529 Beilstein:4(3)1771
  • For a brief feature on uses of the reagent in synthesis, see: Synlett, 709 (2005).
  • Short: EINECS
  • Efficient catalyst for the trifluoromethylation of aldehydes, ketones, imides and imines with (Trifluoromethyl)­trimethyl­silane, B20347: Synlett, 267 (2006).
  • Ligand which has been used in conjunction with Tris(dibenzyl­ideneacetone)­dipalladium(0)­, 12760 in promoting Suzuki cross-coupling reactions of arylboronic acids with aryl and vinyl halides under mild conditions. The system is particularly recommended for coupling reactions with normally unreactive aryl chlorides: J. Am. Chem. Soc., 4070 (2000). The same catalyst system has been found to be effective in the room-temperature cyanation of aryl bromides using zinc cyanide: Synlett, 2237 (2003).
  • Merck: 14,9529
  • Ligand which has been used in conjunction with Tris(dibenzyl­ideneacetone)­dipalladium(0)­, 12760 in promoting Suzuki cross-coupling reactions of arylboronic acids with aryl and vinyl halides under mild conditio

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P231 Handle under inert gas. 在惰性气体中操作。
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S25 Avoid contact with eyes 避免眼睛接触；
Packing GroupI
UN Number UN2845 1993 UN2846
Risk Statements
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 对空气和水分敏感，密封保存。 Air & Moisture Sensitive 充氩，储存温度 2-8℃。
Hazard Codes F,C
Restrict 危险品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling - Catalysis and Inorganic Chemistry
  4. Basic Phosphine Ligands - Cross-Coupling
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Buchwald Ligands Buchwald 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Mitsunobu Reaction
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling 交叉偶联
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  3. Phosphines

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