Borane tetrahydrofuran complex solution 硼烷四氢呋喃络合物

CAS 14044-65-6 MFCD00012429

化学结构图

14044-65-6
SMILES: B.C1CCOC1

化学属性

Mol. FormulaC4H11BO
Mol. Weight86
Density0.898
Flash Point-22°C(lit.)
TSCAYes
Boiling Point66
Solubility起反应
Stability对空气敏感，对湿度敏感
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameBorane tetrahydrofuran complex solution
Beilstein Registry Number3668402
MDL NumberMFCD00012429
PubChem Substance ID24850560
Synonym BORANE TETRAHYDROFURAN COMPLEX SOLUTION, ~1 M IN THF TETRAHYDROFURAN BORANE Borane tetrahydrofuran complex solution 四氫喃硼烷 四氢喃硼烷 硼烷-四氢呋喃 BORANE BORANE-TETRAHYDROFURAN COMPLEX, CA. 1.8M SOLUTION IN TETRAHYDROFURAN, TECH. BTHF Borane-tetrahydrofuran complex, 1M solution tetrahydrofuran BORANE-TETRAHYDROFURAN COMPLEX, 1.5M SOL N IN TETRAHYDROFURAN AND ETHER, TECH. BORANE-TETRAHYDROFURAN COMPLEX 1.0M SO& BORANE TETRAHYDROFURAN COMPLEX BORANE-TETRAHYDROFURAN BORON HYDRIDE-TETRAHYDROFURAN COMPLEX Tetrahydrofuran borane
EC Number237-881-8
CAS Number14044-65-6
Reaxys-RN3668402
Chemical Name Translation硼烷四氢呋喃络合物
LabNetwork Molecule IDLN01358165
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SA} 25mL Sure/Seal Reagents, Boranes, Chemical Synthesis, Organometallic Reagents, Reduction, Synthetic Reagents
  • {SNA} 25mL Sure/Seal Reagents, Boranes, Chemical Synthesis, Organometallic Reagents, Reduction, Synthetic Reagents
  • {SNA} Boranes, Chemical Synthesis, Reduction, Synthetic Reagents

产品应用

  • 用于将聚酰胺纤维表面的酰胺基还原为仲胺。

相关文献及参考

  • Beilstein:17(3/4)24
  • Examples of hydroboration reactions:
  • For other reactions of borane, see Borane-dimethyl­ sulfide complex, L07705.
  • For use in the reduction of carboxylic acids to alcohols, see: Org. Synth. Coll., 7, 221 (1990).
  • Hydroboration, followed by reaction of the trialkylborane with a diazoketone to give a homologated ketone: Org. Synth. Coll., 6, 919 (1988). In situ generation of "disiamyl" borane from 2-methyl-2-butene, and use of this reagent in selective hydroboration reactions: Org. Synth. Coll., 7, 258 (1990). Preparation of di-3-pinanylborane from (-)-ɑ-pinene, and its use in asymmetric hydroborations, see: Org. Synth. Coll., 7, 339 (1990).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H351 Suspected of causing cancer 怀疑致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P303+P361+P353
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+P378
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P301+P330+P331+P310
  • P403+P233
  • P305+P351+P338+P310
Signal word
Safety Statements
Packing GroupI
UN Number
Risk Statements
  • R11 Highly flammable 非常易燃
  • R22 Harmful if swallowed 吞咽有害
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Storage condition 0-10 2-8°C Air & Moisture Sensitive 储存温度2-8℃ 0-10°C
Hazard Codes
Hazard Class4.3/3
Restrict 危险品

其他信息

  • 灭火剂:干粉、二氧化碳、泡沫、1211灭火剂
  • F:1-10-13-34
  • Alfa Aesar:四氢呋喃硼烷,1M在四氢呋喃溶剂中,在氩气保护下储存在ChemSeal密封瓶中密封 Borane-tetrahydrofuran complex, 1M soln. in THF, packaged under Argon in resealable ChemSeal™ bottles(14044-65-6)
  • 爆炸物危险特性:一般使用其溶液; 纯物品不稳定; 其四氢呋喃溶液室温不稳定可爆炸
  • MOL 文件:14044-65-6.mol
  • 可燃性危险特性:受热分解排出辛辣刺激烟雾
  • 下游产品:1-(4-(吡咯烷-1-基)丁基)肼 --> 6-溴-1,2,3,4-四氢异喹啉 --> 1-(4-吗啉基丁基)肼 --> 1-(3-(吡咯烷-1-基)丙基)肼 --> 1-甲基-3-苯基哌嗪 --> 儿萘酚硼烷
  • 储运特性:库房通风低温
  • Acros Organics:硼烷四氢呋喃溶液 Borane-tetrahydrofuran complex, 1M solution in THF, Stabilized, AcroSeal?(14044-65-6)
  • Sigma Aldrich:14044-65-6(sigmaaldrich)
  • 用途一:蒎烯的配套产品，用于原料药孟鲁司特钠、恩替卡韦的生产。
  • 存储注意事项:氮气保护
  • TCI Shanghai:四氢呋喃硼烷(8.5%的四氢呋喃溶液,约0.9Mol/L)(含稳定剂硼氢化钠) Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride)(14044-65-6)
  • 和水剧烈反应。对空气和湿度敏感。
  • 图谱信息:硼烷四氢呋喃络合物(14044-65-6)红外图谱(IR1)
  • 敏感性:Air & Moisture Sensitive
  • 类别:爆炸物品
  • 硼烷四氢呋喃络合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A17619201 硼烷四氢呋喃溶液(+4℃) 100ml 541元 2011/04/16 T2346 硼烷-四氢呋喃络合物(8.5%的四氢呋喃溶液, 约0.9mol/L)(含稳定剂硼氢化钠) Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride) 500ML 2150元 2011/04/16 T2346 硼烷-四氢呋喃络合物(8.5%的四氢呋喃溶液, 约0.9mol/L)(含稳定剂硼氢化钠) Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride) 100ML 760元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Seal™ Reagents 专有包装技术有机金属
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Furans 呋喃
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Aluminum Hydrides - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction

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