COBALT TRICARBONYL NITROSYL 三羰基亚硝酰基钴

CAS 14096-82-3 MFCD00016014

化学结构图

14096-82-3
SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].O=N[Co]

化学属性

Mol. FormulaC3CoNO4
Mol. Weight172.97
Density1.47
Melting Point-1°
TSCANo
Boiling Point48.6°(55° dec.)
Appearance dark red liq.
Stabilityair sensitive, store cold

别名和识别编码

Chemical NameCOBALT TRICARBONYL NITROSYL
Synonym Tricarbonylnitrosylcobalt Tricarbonylnitrosyl-cobalt Tricarbonyl-nitroso-cobalt {uni_hamburg} Cobalt tricarbonyl nitrosyl
MDL NumberMFCD00016014
EC Number237-945-5
CAS Number14096-82-3
Chemical Name Translation三羰基亚硝酰基钴
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分类

  • {uni_hamburg} no charge; metal-organic; metal carbonyl; 1fragment

相关文献及参考

  • Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules Author: Demaison, J.; Hübner, H.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24C Year: 2002 Keyword: Atoms; Molecules and Cluster; Physi

安全信息

Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Packing GroupII
UN Number UN1992
Risk Statements
  • R11 Highly flammable 非常易燃
  • R25 Toxic if swallowed 吞咽有毒
  • R26 Very toxic by inhalation 吸入极毒
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Storage condition Air Sensitive

系列性分类

  1. CVD & ALD Precursors
  2. Cobalt
  1. Organometallics for CVD & ALD
  2. Cobalt

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