Benzo[d][1,3]Dioxol-5-Amine 苯并[d][1,3]二氧杂环戊烯-5-胺

CAS 14268-66-7 MFCD00005832

化学结构图

14268-66-7
SMILES: NC1=CC2OCOC=2C=C1

化学属性

Mol. FormulaC7H7NO2
Mol. Weight137
Boiling Point156°C/30mmHg(lit.)
Melting Point41.0 to 46.0 deg-C
Flash Point142°(287°F)
TSCAYes
Solubility略溶于水

别名和识别编码

Chemical NameBenzo[d][1,3]Dioxol-5-Amine
Synonym 胡椒胺 5-Amino-1,3-benzodioxole; 1,3-Benzodioxol-5-amine 5-Amino-1,3-benzodioxole 3,4-(亚甲二氧基)苯胺
CAS Number14268-66-7
PubChem Substance ID87572747
EC Number238-161-6
Beilstein Registry Number4919
MDL NumberMFCD00005832
Reaxys-RN4919
Chemical Name Translation苯并[d][1,3]二氧杂环戊烯-5-胺
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分类

  • Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Amines, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Beil. 19 ,V,8,389
  • Corp MSDS 1 (2), 2346:A / FT-IR 1 (1), 1225:A / FT-IR 2 (2), 2074:D / FT-NMR 1 (2), 512:A / IR-Spectra (2), 646:F / IR-Spectra (3), 733:G / NMR-Reference 2 (1), 1035:A / RegBook 1 (1), 1415:B / Structure Index 1 , 220:B:4 / Vapor Phase 3 , 1144:D

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
Signal word Warning {} {} {} {} {} {} {TCI}
Storage condition 0-10 Air & Light Sensitive 0-10°C
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
UN Number UN2811
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Packing GroupIII

系列性分类

  1. C7 - Amines
  1. C10 to C11 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C2 to C6

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