1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride [1,2-双(二苯基膦)乙烷]二氯化镍(II)
CAS 14647-23-5 MFCD00013313
化学结构图
SMILES: [Cl-].[Cl-].[Ni+2].c1ccc(P(CCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1
化学属性
| Mol. Formula | C26H24Cl2NiP2 |
|---|---|
| Mol. Weight | 528 |
| TSCA | No |
| Melting Point | 263-265 |
| Density | 1.422 |
| Solubility | 不溶 |
别名和识别编码
| Chemical Name | 1,2-Bis(Diphenylphosphino)Ethane Nickel(II) Chloride |
|---|---|
| CAS Number | 14647-23-5 |
| Alfabeta Name | BISDIPHENYLPHOSPHINOETHANENICKELCHLORIDE II12(())-, |
| MDL Number | MFCD00013313 |
| Synonym | 1,2-Ethylenebis(diphenylphosphine)nickel dichloride 1,2-Ethylenebis(diphenylphosphine)nickel dichloride Nickel 1,2-Bis(diphenylphosphino)ethane dichloride [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride dppeNiCl2 Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) Nickel 1,2-Bis(diphenylphosphino)ethane dichloride [1,2-双(二苯基膦)乙烷]二氯化镍(II) dppeNiCl2 |
| PubChem Substance ID | 9871585 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| Reaxys-RN | 14761473 |
| Chemical Name Translation | [1,2-双(二苯基膦)乙烷]二氯化镍(II) |
| LabNetwork Molecule ID | LN00173968 |
| InChI | InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel, Nickel Catalysts, Non-Precious Metal Catalysis
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel, Non-Precious Metal Catalysis
产品应用
- 有机金属催化剂。
安全信息
- S22 Do not breathe dust 不要吸入粉尘；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R42/43
- R45 May cause cancer 可能致癌
GHS Symbol
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
- P301+P312+P330
- P302+P350
- P304+P340+P312
- P305+P351+P338
- P305+P351+P338+P337+P313
- P308+P313
- P337+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302+H312+H332
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H312 Harmful in contact with skin 皮肤接触有害
- H302 Harmful if swallowed 吞食有害
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H350 May cause cancer 可能致癌
- H319 Causes serious eye irritation 严重刺激眼睛
其他信息
- 在空气中稳定。
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