L-Glutamic acid 5-methyl ester L-谷氨酸-5-甲酯

CAS 1499-55-4 MFCD00002632

化学结构图

1499-55-4
SMILES: COC(=O)CC[C@H](N)C(=O)O

化学属性

Mol. FormulaC6H11NO4
Mol. Weight161.16
Density1.242
Melting Point182°C
TSCANo
Refractive index29 ° (C=2, 6mol/L HCl)
Boiling Point316.1°C at 760 mmHg

别名和识别编码

Chemical NameL-Glutamic acid 5-methyl ester
CAS Number1499-55-4
Alfabeta NameGLUTAMICACIDMETHYLESTER L5--
MDL NumberMFCD00002632
EC Number216-110-9
Beilstein Registry Number1725252
Synonym H-Glu(OMe)-OH {LY} H-Glu(OMe)-OH PGMGT PMLG polymer poly(gamma-methyl L-glutamate) poly(gamma-methyl-L-glutamate) poly-gamma-methylglutamate poly-gamma-methylglutamic acid {} {LY} H-Glu(OMe)-OH {} {} {LY} H-Glu(OMe)-OH {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} H-Glu(OMe)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID68662
Reaxys-RN466824
Chemical Name TranslationL-谷氨酸-5-甲酯
InChIKeyZGEYCCHDTIDZAE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009497
InChIInChI=1S/C6H11NO4/c1-11-5(8)3-2-4(7)6(9)10/h4H,2-3,7H2,1H3,(H,9,10)/t4-/m0/s1
Canonical SMILESN[C@@H](CCC(OC)=O)C(O)=O
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分类

  • {SNA} Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Glutamic Acid, Peptide Chemistry
  • {SNA} Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Glutamic Acid, Peptide Chemistry

相关文献及参考

  • Beilstein:4(4)3033

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • Acros Organics:L-谷氨酸-5-甲酯 L-Glutamic acid 5-methyl ester, 99%(1499-55-4)
  • 上游原料:甲醇 --> 乙醚 --> 氧氯化硫 --> 氢氧化铵 --> 谷氨酸
  • TCI Shanghai:L-谷氨酸-5-甲酯 5-Methyl L-Glutamate,>;98.0%(T)(1499-55-4)
  • 图谱信息:L-谷氨酸-5-甲酯(1499-55-4)红外图谱(IR2) L-谷氨酸-5-甲酯(1499-55-4)核磁图( 13 CNMR) L-谷氨酸-5-甲酯(1499-55-4)红外图谱(IR1) L-谷氨酸-5-甲酯(1499-55-4)质谱(MS) L-谷氨酸-5-甲酯(1499-55-4)核磁图( 1 HNMR) L-谷氨酸-5-甲酯(1499-55-4)Raman光谱
  • MSDS 信息:L-Glutamic acid gamma-methyl ester(1499-55-4).msds
  • 外观性质:白色粉末。
  • L-谷氨酸-5-甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1690 L-谷氨酸5-甲酯 5-Methyl L-Glutamate 5G 234元 2014/06/02 M1690 L-谷氨酸5-甲酯 5-Methyl L-Glutamate 25G 643元 2010/06/21 228310250 L-谷氨酸-5-甲酯 L-Glutamic acid 5-methyl ester 99% 25 GR 1087元
  • 方法一:由L-谷氨酸与甲醇酯化而得。将甲醇、硫酸和L-谷氨酸在20℃酯化反应4h即得L-γ-谷氨酸甲酯。
  • 用途一:该品为乙酰谷氨酰胺的中间体。
  • 比旋光度:13 ° (c=1, H2O 24 °C)
  • Alfa Aesar:L-谷氨酸5-甲酯,99% L-Glutamic acid 5-methyl ester, 99%(1499-55-4)
  • 下游产品:L-谷氨酰胺 --> N-乙酰-L-谷氨酰胺
  • Sigma Aldrich:1499-55-4(sigmaaldrich)
  • MOL 文件:1499-55-4.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Glutamic Acid - Amino Acid Derivatives
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Glutamic Acid - Amino Acid Derivatives
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. Methyl Ester of Amino Acids

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