Diiron nonacarbonyl 九羰基二铁
CAS 15321-51-4 MFCD00151465
化学结构图
SMILES: O#[C]1[Fe]2(C#O)(C#O)(C#O)[C](#O)[Fe]1(C#O)(C#O)(C#O)[C]2#O
化学属性
| Mol. Formula | Fe2(CO)9 |
|---|---|
| Mol. Weight | 363.78 |
| Melting Point | ca 100° dec. |
| Density | 2.85 |
| TSCA | Yes |
| Appearance | yellow to orange xtl. |
| Stability | air sensitive, store cold |
别名和识别编码
| Chemical Name | Diiron nonacarbonyl |
|---|---|
| Synonym | di-Eisennonacarbonyl Diiron nonacarbonyl Tri-μ-carbonylhexacarbonyldiiron Di-ironnonacarbonyl Fe2 (CO)9 Enneacarbonyldiiron Iron enneacarbonyl Nonacarbonyldiiron Iron, tri μ carbonylhexacarbonyldi-, (Fe Fe) Iron, tri-μ-carbonylhexacarbonyldi-, (Fe-Fe) nonacarbonyldiiron Diiron enneacarbonyl Dieisenenneacarbonyl Diiron nonacarbonylIron nonacarbonyl Iron carbonyl (Fe2(CO)9) Eisencarbonyl C9Fe2O9 Dieisennonacarbonyl 二壬羰基铁 tri μ carbonylhexacarbonyldiiron Enneacarbonyldiiron Nonacarbonyldieisen |
| MDL Number | MFCD00151465 |
| EC Number | 239-359-5 |
| CAS Number | 15321-51-4 |
| PubChem Substance ID | 24853499 |
| InChIKey | JZWULYOLCXQALO-UHFFFAOYSA-N |
| Chemical Name Translation | 九羰基二铁 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron, Non-Precious Metal Catalysis
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron
- {uni_hamburg} no charge; metal-organic; other heterocycle; fused rings; 4ring; metal carbonyl; 1fragment
相关文献及参考
- Short: III/7c3 Title: Crystal Structure Data of Inorganic Compounds: Key Element: C Author: Pies, W.; Weiss, A.; Boehm, H.-P.; Meyer, H.J. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/7c3 Page: 1-291 Year: 1979 ISBN: 3-540-09491-1 ISBN: 978-3-540-09491-3 Internet Resource: DOI:10.1007/b85782 RefComment: 16 figs., XXVII, Hardcover Abstract: Volume III/7 contains structure data on those compounds which contain at least one of the elements F, Cl, Br, I, O, N, and P and cannot be called "organic". The structure data of the remaining inorganic compounds and the elements are dealt with in volumes III/6 and III/14, while the organic compounds are treated in volumes III/5 and III/10. The systematic arrange-ment is based on the anions ordered according to "key elements", since this system allows the arrangement of the crystal structure data in such a way that both chemical and crystallographical relationships can be recognized. Structure data are compiled as completely as possible for all inorganic substances, where crystal structures have been examined by means of X-ray, neutron, and electron diffraction,and for which at least the lattice constants have been determined.
- Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.
- Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Y
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- P422 Store contents under… 存储目录在…之下。
- P231+P232
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- H228 Flammable solid 易燃固体
- H331 Toxic if inhaled 吸入中毒
- H301 Toxic if swallowed 吞食有毒
- H301+H331
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- R11 Highly flammable 非常易燃
- R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
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