4-(Azidosulfonyl)benzoic acid 4-(叠氮磺酰基)苯甲酸

CAS 17202-49-2 MFCD00041753

化学结构图

17202-49-2
SMILES: [N-]=[N+]=NS(=O)(=O)C1C=CC(=CC=1)C(O)=O

化学属性

Mol. FormulaHO2CC6H4SO2N3
Mol. Weight227.20
Melting Point180 °C (dec.)(lit.)

别名和识别编码

Chemical Name4-(Azidosulfonyl)benzoic acid
Synonym 4-(叠氮磺酰)苯甲酸 4-羧基苯磺酰叠氮
MDL NumberMFCD00041753
PubChem Substance ID24860776
CAS Number17202-49-2
Chemical Name Translation4-(叠氮磺酰基)苯甲酸
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分类

  • {SNA} Azidation/Diazo Transfer, Azides, Building Blocks, C-X Bond Formation (Non-Halogen), Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Copper Click Chemistry, Nitrogen Compounds, Organic Azides, Organic Building Blocks, Synthetic Reagents, Various Azides
  • {SNA} Azidation/Diazo Transfer, Azides, Building Blocks, C-X Bond Formation (Non-Halogen), Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Nitrogen Compounds, Organic Azides, Organic Building Blocks, Synthetic Reagents,

相关文献及参考

  • A. J. P. Mortimer, et al., Org. Lett. 10 , 5477-5480, (2008)
  • B. Gaspar, et al., Synthesis 24 , 3839-3845, (2007)
  • F. Fringuelli, et al., Synthesis 5 , 646-650, (2000)
  • FT-IR 2 (2), 3301:A / RegBook 1 (2), 2247:L / Structure Index 1 , 352:C:8
  • Fieser 2 ,62 / Fieser 17 ,66
  • N. Shangguan, et al., J. Am. Chem. Soc. 125 , 7754-7755, (2003)
  • R. De Simone, et al., J. Med. Chem. 54 , 1565-1575, (2011)
  • X. Zhang, et al., Bioconjug. Chem. 20 , 197-200, (2009)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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