Vinylphosphonic acid 乙烯基膦酸

CAS 1746-03-8 MFCD00043866

化学结构图

1746-03-8
SMILES: C=CP(=O)(O)O

化学属性

Mol. FormulaC2H5O3P
Mol. Weight108.03
Density1.37
Melting Point36 °C (Lit. dry VPA) (lit.)
Refractive indexn20/D 1.473
Flash Point>;230 °F
Appearance colorless to pale-yellow liq.
Boiling Point98

别名和识别编码

Chemical NameVinylphosphonic acid
CAS Number1746-03-8
EC Number217-123-2
Beilstein Registry Number1741622
MDL NumberMFCD00043866
Reaxys-RN1741622
PubChem Substance ID168725
Synonym Ethenephosphonic acid Ethylenephosphonic acid ITC 467 Phosphonic acid, ethenyl- Phosphonic acid, vinyl- VINYLPHOSPHONIC ACID 65 %, TECHNICAL VINYLPHOSPHONIC ACID 90 %, PURE Vinyl phosphonic acid, 98 % (HPLC) Vinyl-phosphonic acid Vinylphosophonicacid Vinylphosphonic Acid (contains Phosphoric Acid, Polyvinylphosphonic Acid and Methoxyethylphosphonic Acid) Vinylphosphonic acid Vinylphosphonic acid (contains phosphoric acid, polyvinylphosphonic acid and methoxyethylphosphonic acid) (stabilized with HQ) Vinylphosphonsure ethenephosphonicacid ethenyl-phosphonicaci ethenylphosphonicacid ethylenephosphonicacid vinyl-phosphonicaci vinylphosphonic acid {} {} {} {} {} {} {} {
Chemical Name Translation乙烯基膦酸
InChIKeyBQMQLJQPTQPEOV-UHFFFAOYSA-N
LabNetwork Molecule IDLN01743949
InChIInChI=1S/C2H5O3P/c1-2-6(3,4)5/h2H,1H2,(H2,3,4,5)
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分类

  • {SNA} Materials Science, Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers
  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonic/Phosphinic Acids, Phosphorus Compounds
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Monomers, Polymer Science, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers, 材料科学
  • {SA} Building Blocks,

相关文献及参考

  • Beil. 4 ,IV,3560
  • FT-IR 2 (1), 1558:B / Structure Index 1 , 170:D:2
  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P304+P340
  • P305+P354+P338
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
RTECSSZ7903500
UN Number 3265
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
Packing GroupIII
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1953-  Volume(issue)/page/year: 39,380,1991

其他信息

  • 乙烯基膦酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 V0068 乙烯磷酸酯(含磷酸,聚乙烯磷酸和甲氧基乙基磷酸) Vinylphosphonic Acid (contains Phosphoric Acid, Polyvinylphosphonic Acid and Methoxyethylphosphonic Acid) 25G 1230元 2014/06/02 V0068 乙烯磷酸酯(含磷酸,聚乙烯磷酸和甲氧基乙基磷酸) Vinylphosphonic Acid (contains Phosphoric Acid, Polyvinylphosphonic Acid and Methoxyethylphosphonic Acid) 250G 7630元
  • Sigma Aldrich:1746-03-8(sigmaaldrich)
  • TCI Shanghai:or 乙烯基磷酸 Vinylphosphonic Acid (contains Phosphoric Acid, Polyvinylphosphonic Acid and Methoxyethylphosphonic Acid),>;95.0%(T)(1746-03-8)
  • MOL 文件:1746-03-8.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonic/Phosphinic Acids - Phosphorus Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Vinyl Halides, Amines, Amides, and Other Vinyl Monomers - Monomers
  1. Phosphine
  2. Phosphorus
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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