(R)-(+)-6,6-Dibromo-2,2-Bis(Methoxymethoxy)-1,1-Binaphthyl (R)-6,6’-二溴-2,2’-双(甲氧基甲氧基)-1,1’-联萘

CAS 179866-74-1 MFCD03788936

化学结构图

179866-74-1
SMILES: COCOC1C=CC2C=C(Br)C=CC=2C=1C1C2C=CC(Br)=CC=2C=CC=1OCOC

化学属性

Mol. Formula(CH3OCH2OC10H5Br)2
Mol. Weight532.22
Melting Point129-133 °C(lit.)
Appearance white to light-yellow pwdr.

别名和识别编码

Chemical Name(R)-(+)-6,6-Dibromo-2,2-Bis(Methoxymethoxy)-1,1-Binaphthyl
CAS Number211560-97-3
Synonym (1R)-6,6'-dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene (S)-(-)-6,6′-二溴-2,2′-双(甲氧基甲氧基)-1,1′-联萘
MDL NumberMFCD03788936
PubChem Substance ID354333593
Chemical Name Translation(R)-6,6’-二溴-2,2’-双(甲氧基甲氧基)-1,1’-联萘
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分类

  • Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

产品应用

  • An intermediate in the symmetric synthesis of BINOL-terpyridine ligands.

相关文献及参考

  • Rajaram, A., et al.: Org. Lett., 8, 2019 (2006),
  • Wong, K., et al.: Coord. Chem. Rev., 251, 2477 (2007),

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
  • H318 Causes serious eye damage 严重伤害眼睛
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Danger
Safety Statements
  • S25 Avoid contact with eyes 避免眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
Risk Statements
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINOLs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINOLs - Privileged Ligands and Complexes
  1. BINOL
  2. Oxygen

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