2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine 2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-D]恶唑啉-2-基]吡啶
CAS 185346-09-2 MFCD05861599
化学结构图
SMILES: C1[C@H]2OC(=N[C@H]2C2C=CC=CC=21)C1C=CC=C(N=1)C1=N[C@@H]2[C@@H](CC3C=CC=CC=32)O1
化学属性
| Mol. Formula | C25H19N3O2 |
|---|---|
| Mol. Weight | 393.44 |
| Melting Point | 276-281 |
| Appearance | white-light yellow pwdr. white to off-white pwdr. |
| Stability | store cold |
别名和识别编码
| Chemical Name | 2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine |
|---|---|
| Synonym | (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑 (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑 (3aS,8aR)-in-pybox Dimethlyammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2′-bis(dip-tolylphosphino)1,1′-binaphthyl]diruthenate(ΙΙ) (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑 (3aS,8aR)-in-pybox Dimethlyammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(dip-tolylphosphino)1,1'-binaphthyl]diruthenate(ΙΙ) (3aS,8aR)-in-pybox (3aS,8aR)-in-pybox Dimethlyammonium dichlorotri(μ-chloro)bis[(S)-(−)-2,2′-bis(dip-tolylphosphino)1,1′-binaphthyl]diruthenate(ΙΙ) 2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-d]噁唑啉-2-基]吡啶 |
| MDL Number | MFCD05861599 |
| CAS Number | 185346-09-2 |
| Chemical Name Translation | 2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-D]恶唑啉-2-基]吡啶 |
| PubChem Substance ID | 329760573 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX
相关文献及参考
- 1. E. Milczek, et al., , Enantioselective C-H amination using cationic ruthenium(II)-pybox catalysts Angew. Chem. Int. Ed. Engl. 47 , 6825-6828, (2008)
- 2. D. A. Evans and K. R. Fandrick, , Catalytic Enantioselective Pyrrole Alkylations of a,ß-Unsaturated 2-Acyl Imidazoles Org. Lett. 8 , 2249-2252, (2006)
- 3. M. K. Tse, et al., , Ruthenium-catalyzed asymmetric epoxidation of olefins using H2O2, part I: synthesis of new chiral N,N,N-tridentate pybox and pyboxazine ligands and their ruthenium complexes Chem. Eur. J. 12 , 1855-1874, (2006)
安全信息
- H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
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