N-aminophthalimide N-氨基邻苯二甲酰二胺

CAS 1875-48-5 MFCD00005895

化学结构图

1875-48-5
SMILES: NN1C(=O)c2ccccc2C1=O

化学属性

Mol. FormulaC8H6N2O2
Mol. Weight162.15
Melting Point200-202°C
TSCANo
Boiling Point348.6°C at 760 mmHg
Flash Point164.6°C

别名和识别编码

Chemical NameN-aminophthalimide
Synonym 2-Aminoisoindoline-1,3-dione {LY} 2-Aminoisoindoline-1,3-dione N-aminophthalimide {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Aminoisoindoline-1,3-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Am
MDL NumberMFCD00005895
PubChem Substance ID74645
Beilstein Registry Number383756
CAS Number1875-48-5
EC Number217-505-9
Reaxys-RN383756
Alfabeta NameAMINOISOINDOLEDIONE HH21132()-----,
Chemical Name TranslationN-氨基邻苯二甲酰二胺
InChIKeyKSILMCDYDAKOJD-UHFFFAOYSA-N
LabNetwork Molecule IDLN00184716
Canonical SMILESO=C1N(N)C(C2=C1C=CC=C2)=O
InChIInChI=1S/C8H6N2O2/c9-10-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H,9H2
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks
  • Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks

相关文献及参考

  • May be oxidized with lead(IV) acetate to "phthalimidonitrene", which adds to alkenes to give aziridines. The phthalimido group can be cleaved with hydrazine hydrate: J. Chem. Soc. (C), 576 (1970); J. Am. Chem. Soc., 92, 1784 (1970); Helv. Chim. Acta, 55, 1276 (1972); Org. Synth. Coll., 6, 56 (1988). Addition to cyclopentadienes leads to substituted pyridines after ring-opening with base: Heterocycles, 22, 1369 (1984). Addition to the (racemic) acrylic ester below shows an extremely high facial selectivity, adding to the less hindered side (290:1): Helv. Chim. Acta, 72, 1095 (1989).
  • Aziridination has also been achieved in high yield by electrochemical oxidation: J. Am. Chem. Soc., 124, 530 (2002).

安全信息

GHS Symbol
Precautionary statements
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
  • P302+P350
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P304+P340
  • P304+P340+P342+P311
  • P304+P341
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P333+P313
  • P333+P317
  • P337+P313
  • P337+P317
  • P342+P311
  • P342+P316
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Danger {} {} {} {} {} {} {} {TCI}
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42/43
Warnings IRRITANT
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 图谱信息:氨基邻苯二甲胺(1875-48-5)核磁图( 1 HNMR) 氨基邻苯二甲胺(1875-48-5)红外图谱(IR2) 氨基邻苯二甲胺(1875-48-5)红外图谱(IR1) 氨基邻苯二甲胺(1875-48-5)质谱(MS) 氨基邻苯二甲胺(1875-48-5)核磁图( 13 CNMR)
  • Sigma Aldrich:1875-48-5(sigmaaldrich)
  • TCI Shanghai:N-氨基邻苯二甲酰亚胺 N-Aminophthalimide,>;98.0%(LC)(1875-48-5)
  • Acros Organics:N-氨基邻苯二甲酰亚胺 N-Aminophthalimide, tech., 90%(1875-48-5)
  • F:9
  • MOL 文件:1875-48-5.mol
  • 氨基邻苯二甲胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0843 N-氨基邻苯二甲酰亚胺 N-Aminophthalimide 5G 403元 2014/06/02 A0843 N-氨基邻苯二甲酰亚胺 N-Aminophthalimide 25G 1190元 2010/06/21 176330050 氨基邻苯二甲胺 N-Aminophthalimide 90%, tech. 5 GR 683元
  • Alfa Aesar:N-氨基邻苯二甲酰亚胺,95% N-Aminophthalimide, 94%(1875-48-5)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amidates/Imidates - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters
  6. C8 to C9

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