3,5-Diiodo-L-Tyrosine Dihydrate 3,5-二碘-L-酪氨酸 二水合物

CAS 18835-59-1 MFCD00016542

化学结构图

18835-59-1
SMILES: O.O.N[C@@H](CC1=CC(I)=C(O)C(I)=C1)C(O)=O |&1:3|

化学属性

Mol. FormulaC9H9I2NO3.2H2O
Mol. Weight432.98(as Anhydrous)
Melting Point200 °C (dec.)(lit.)
Density1.422
Solubility略溶于水
Appearance crystalline
Refractive index1.2 ° (C=5, 1mol/L HCl)

别名和识别编码

Chemical Name3,5-Diiodo-L-Tyrosine Dihydrate
MDL NumberMFCD00016542
PubChem Substance ID87567261
Beilstein Registry Number2218691
CAS Number18835-59-1
EC Number206-092-0
Reaxys-RN2218691
Synonym 3',5'-Diiodo-L-tyrosine 3,5-DIIODO-4-HYDROXY-BETA-PHENYLALANINE 3,5-DIIODO-BETA(4-HYDROXYPHENYL)ALANINE 3,5-DIIODO-L-TYROSINE 3,5-Diiod-L(-)-tyrosin-Dihydrat 3,5-Diiodo-4-hydroxy-β-phenylalanine 3,5-Diiodo-L-tyrosine 3,5-Diiodo-L-tyrosine dihydrate 3,5-Diiodotyrocine 3,5-Iodo-L-tyrosine 3,5-L-Diiodotyrosine 3,5-二碘酪胺酸 4-HYDROXY-3,5-DIIODOPHENYLALANINE, 2-AMINO-3-(4-HYDROXY-3,5-DIIODOPHENYL)PROPIONIC ACID AGONTAN Agontan DIT DITYRIN H-3,5-DIIODO-TYR-OH Iodogorgoic acid L-3,5-Diiodotyrosine L-Β-(3,5-二碘-4-羟基苯基)-Α-氨基丙酸 Tryosine, 3,5-diiodo- diiodotyrosine 二碘酪氨酸
Chemical Name Translation3,5-二碘-L-酪氨酸 二水合物
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分类

  • A - H, Amino Acids, Biochemicals and Reagents, Diiodotyrosine transaminase, Enzyme Substrates, Enzymes, Inhibitors, and Substrates, Modified Amino Acids, Substrates by Enzyme
  • {SNA} A - H,
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carboxylic acid; alcohol; chiral; 1fragment
  • {SNA} A - H, Amino Acids, Biochemicals and Reagents, Diiodoty
  • {SA} Amino Acid Derivatives, Biochemicals and Reagents, Chemical Biology, Chemical Synthesis, Diiodotyrosine transaminase, Enzyme Substrates, Enzymes, Inhibitors, and Substrates, Peptide Chemistry, Substrates by Enzyme, Tyrosine, Tyrosine Derivatives, Unnatural Amino Acid Derivatives
  • {SNA} A - H,

相关文献及参考

  • 1. Nakano, M. J. Biol. Chem. 242 , 73, (1967) 摘要
  • 2. Nakano, M. Meth. Enzymol. 17A , 660, (1970)
  • 3. Balsam, A., et al., Formation of diiodotyrosine from thyroxine. Ether-link cleavage, an alternate pathway of thyroxine metabolism. J. Clin. Invest. 72 , 1234-1245, (1983) 摘要
  • Beil. 14 ,619 / Beil. 14 ,IV,2372
  • IR-Spectra (2), 874:D / IR-Spectra (3), 998:G / NMR-Reference 2 (2), 259:B / RegBook 1 (2), 1847:G / Structure Index 1 , 296:C:4
  • Short: III/20c Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Zr ... Bi. Diagrams, Structure formulas, Indexes Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20c Year: 1989 Keyword: NQR ISBN: 3-540-18490-2 ISBN: 978-3-540-18490-4 Internet Resource: DOI:10.1007/b35374 RefComment: 562 figs., IX,802 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C
UN Number 2811

其他信息

  • 外观性质:淡黄色粉末。熔点:200 ºC 比旋光度:-20.7 º
  • MOL 文件:300-39-0.mol
  • 3,5-二碘-L-酪氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D0612 3,5-二碘-L-酪氨酸二水合物 3,5-Diiodo-L-tyrosine Dihydrate 25G 1020元 2010/06/21 225610100 3,5-二碘-L-酪氨酸 3,5-Diiodo-L-tyrosine dihydrate 99% 10 GR 518元 2010/06/21 225610500 3,5-二碘-L-酪氨酸 3,5-Diiodo-L-tyrosine dihydrate 99% 50 GR 1512元
  • TCI Shanghai:3,5-二碘-L-酪氨酸 二水合物 3,5-Diiodo-L-tyrosine Dihydrate,>;98.0%(T)(300-39-0)
  • 下游产品:L-甲状腺素
  • Sigma Aldrich:300-39-0(sigmaaldrich)
  • color:white
  • 比旋光度:-20.7 ° (c=2.5, 0.1N NaOH/H2O)
  • Acros Organics:L-3,5- 二碘酪氨酸 3,5-Diiodo-L-tyrosine dihydrate, 99%(300-39-0)
  • 图谱信息:3,5-二碘-L-酪氨酸(300-39-0)质谱(MS) 3,5-二碘-L-酪氨酸(300-39-0)红外图谱(IR2) 3,5-二碘-L-酪氨酸(300-39-0)红外图谱(IR1) 3,5-二碘-L-酪氨酸(300-39-0)核磁图( 1 HNMR)
  • MSDS 信息:3,5-Diiodo-L-tyrosine dihydrate(300-39-0).msds
  • F:8

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. A - H - Modified Amino Acids
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. A - H - Modified Amino Acids
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Volumetric Concentrates (e.g. FIXANAL®) - Titration
  5. Salt Concentrates - Volumetric Concentrates (e.g. FIXANAL®)
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Enzymes, Inhibitors, and Substrates - Biochemicals and Reagents
  4. Enzyme Substrates - Enzymes, Inhibitors, and Substrates
  5. Substrates by Enzyme - Enzyme Substrates
  6. Diiodotyrosine transaminase - Substrates by Enzyme
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Unnatural Amino Acid Derivatives 人工合成氨基酸
  5. Tyrosine Derivatives - Unnatural Amino Acid Derivatives
  1. Medical Research Areas
  2. Metabolism
  3. Endogenous Metabolite  (内源性代谢物)

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