N,N,N,N-Tetramethyl-S-(1-Oxido-2-Pyridyl)Thiuronium Hexafluorophosphate N,N,N,N-四甲基-S-(1-氧代-2-吡啶基)硫脲六氟磷酸盐(HOTT)

CAS 212333-72-7 MFCD05865266

化学结构图

212333-72-7
SMILES: CN(C)C(=[S+]C1=CC=CC=[N+]1[O-])N(C)C.F[P-](F)(F)(F)(F)F

化学属性

Mol. FormulaC10H16F6N3OPS
Mol. Weight371
Melting Point120-125
TSCANo

别名和识别编码

Chemical NameN,N,N,N-Tetramethyl-S-(1-Oxido-2-Pyridyl)Thiuronium Hexafluorophosphate
Synonym N,N,N′,N′-四甲基-S-(1-氧代-2-吡啶基)硫脲六氟磷酸盐 N,N,N',N'-Tetramethyl-S-(1-oxido-2-pyridyl)thiuronium hexafluorophosphate N,N,N′,N′-四甲基-S-(1-氧代-2-吡啶基)硫脲六氟磷酸盐 S-(2-吡啶基)-N,N,N′,N′-四甲基硫脲 N-氧化物六氟磷酸盐
MDL NumberMFCD05865266
PubChem Substance ID135726923
CAS Number212333-72-7
Reaxys-RN8175482
Chemical Name TranslationN,N,N,N-四甲基-S-(1-氧代-2-吡啶基)硫脲六氟磷酸盐(HOTT)
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分类

  • {SA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
  • {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents

相关文献及参考

  • 1. Bryan Knuckley, et al Biochemistry 49 , 4852-4863, (2010) 摘要
  • 2. Erwin Hohn, et al Eur. J. Org. Chem. 22 , 3765-3782, (2009)
  • 3. Erwin Hohn and Joerg Pietruszka Adv. Synth. Catal. 346 , 863-866, (2004)
  • 4. Philip Garner, et al Tetrahedron Asymmetry 14 , 2883-2887, (2003)
  • 5. Fernando Albericio, et al Tetrahedron 57 , 9607-9613, (2001)
  • 6. M. A. Bailen, et al Tetrahedron Lett. 41 , 9809-9813, (2000)
  • 7. M.A. Bailen et al. J. Org. Chem. 64 , 8936, (1999) 摘要
  • 8. F. Albericio et al. Tetrahedron 57 , 9607, (2001)

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition Moisture Sensitive <;0 <0°C
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
GHS Symbol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Coupling - Synthetic Reagents
  4. Phosphonium/Uronium/Formamidinium - Coupling
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Peptide Coupling - Peptide Chemistry
  5. Phosphonium/Uronium/Formamidinium - Peptide Coupling

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