(S)-(-)-2-Azetidinecarboxylic Acid (S)-(-)-2-羧基环丁胺

CAS 2133-34-8 MFCD00005166

化学结构图

2133-34-8
SMILES: O=C(O)[C@@H]1CCN1

化学属性

Mol. FormulaC4H7NO2
Mol. Weight101.10
Melting Point217°C
TSCANo
Solubility5 G/100 ML
Appearance 白色结晶。熔点217℃。
Refractive index-122 ° (C=4, H2O)
Density1.422
Boiling Point189.47 °C at 760 mmHg

别名和识别编码

Chemical Name(S)-(-)-2-Azetidinecarboxylic Acid
CAS Number2133-34-8
Alfabeta NameAZETIDINECARBOXYLICACID S2(())-----
MDL NumberMFCD00005166
Synonym L-Azetidine-2-carboxylic acid {LY} L-Azetidine-2-carboxylic acid {} {LY} L-Azetidine-2-carboxylic acid {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Azetidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID16486
Beilstein Registry Number80678
EC Number218-362-5
Merck Number908
Chemical Name Translation(S)-(-)-2-羧基环丁胺
Reaxys-RN80678
Wiswesser Line NotationT4MTJ BVQ -L
LabNetwork Molecule IDLN00009449
InChIInChI=1S/C4H7NO2/c6-4(7)3-1-2-5-3/h3,5H,1-2H2,(H,6,7)/t3-/m0/s1
Canonical SMILESO=C([C@H]1NCC1)O
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分类

  • {SNA} AN-AZ, Angiogenesis Regulators, Bioactive Small Molecules, Cell Biology, Cell Signaling and Neuroscience, Cytoskeleton and Extracellular Matrix, Extracellular Matrix
  • {SNA} AN-AZ, Angiogenesis Regulators, Bioactive Small Molecules,
  • {SNA} Angiogenesis Regulators, Cytoskeleton and Extracellular Matrix, Extracellular Matrix, 细胞信号转导和神经科学, 细胞生物学
  • {SNA} AN-AZ, Asymmetric Synthesis, Bioactive Small Molecules, Cell Biology, Chemical Biology, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Others, Peptide Chemistry, Proline-Based Organocatalysts, Unnatural Amino

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSCM4310500
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Hazard Codes Xi
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
Signal word Warning
GHS Symbol
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GDA2 "CRC Handbook of Antibiotic Compounds," Vols.1- ,  Berdy, J., Boca
   Raton, FL, CRC Press, 1980-  Volume(issue)/page/year: 8(1),101,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 300 mg/kg
SEX/DURATION            : female 8-10 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 14,248,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 300 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   SEIJBO Senten Ijo.  Congenital Anomalies.  (Nippon Senten Ijo Gakkai, c/o
   Kinki Daigaku Igakubu Kaibagaku Kyoshitsu, 380 Nishiyama, Sayama-cho,
   Miram

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 300 mg/kg
SEX/DURATION            : female 11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 23,365,1981

TYPE OF TEST            : TDLo - Lowest published toxic do

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • MSDS 信息:L-2-Azetidinecarboxylic acid(2133-34-8).msds
  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
  • Acros Organics:(S)-(-)-2-Azetidinecarboxylic acid, 99+%(2133-34-8)
  • 比旋光度:-125 ° (c=1, water 25 °C)
  • 类别:有毒物品
  • 毒性分级:中毒
  • Hazard Note:Irritant
  • 储运特性:通风低温干燥
  • (S)-(-)-2-羧基环丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 100MG 727元 2014/06/02 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 1G 4160元 2010/06/21 105142500 (S)-(-)-2-羧基环丁胺 (S)-(-)-2-Azetidinecarboxylic acid 99+% 250 MG 1762元
  • (S)-(-)-2-羧基环丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 100MG 735元 2011/04/16 A1043 L-氮杂环丁烷-2-羧酸[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline] 1G 4210元 2010/06/21 105142500 (S)-(-)-2-羧基环丁胺 (S)-(-)-2-Azetidinecarboxylic acid 99+% 250 MG 1762元
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • TCI Shanghai:(S)-(-)-2-羧基环丁胺[L-脯氨酸的拮抗物] L-Azetidine-2-carboxylic Acid [Antagonist of L-Proline],>;98.0%(T)(2133-34-8)
  • 急性毒性:皮下-小鼠 LD50: 1000 毫克/公斤
  • 上游原料:盐酸 --> 乙酸乙酯 --> 甲醇 --> 乙醚 --> 四氢呋喃 --> 二氯甲烷 --> 氧氯化硫 --> 石油醚 --> 碳酸钾 --> 碳酸氢钠 --> 钯 --> 氯化铵 --> 乙腈 --> 二甲基亚砜 --> 叔丁醇钾 --> S-1-苯乙胺 --> 2-溴乙醇 --> 溴乙腈
  • Alfa Aesar:(S)-(-)-氮杂环丁烷-2-羧酸,99% (S)-(-)-Azetidine-2-carboxylic acid, 99%(2133-34-8)
  • MOL 文件:2133-34-8.mol
  • Sigma Aldrich:2133-34-8(sigmaaldrich)

系列性分类


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