N-Hydroxy-5-Norbornene-2,3-Dicarboxylic Acid Imide N-羟基-5-降冰片烯-2,3-二甲酰亚胺

CAS 21715-90-2 MFCD00065691

化学结构图

21715-90-2
SMILES: O=C1[C@H]2[C@H]3C=C[C@H](C3)[C@H]2C(=O)N1O

化学属性

Mol. FormulaC9H9NO3
Mol. Weight179
Melting Point165-170
TSCAYes
Density1.574

别名和识别编码

Chemical NameN-Hydroxy-5-Norbornene-2,3-Dicarboxylic Acid Imide
MDL NumberMFCD00065691
Synonym HONBendo-N-Hydroxybicyclo[2.2.1]hept-5-ene-2,3-dicarboximide N-羟基-5-降冰片稀-2,3-二酰亚胺
EC Number244-538-6
CAS Number21715-90-2
Beilstein Registry Number13540
PubChem Substance ID24853563
Chemical Name TranslationN-羟基-5-降冰片烯-2,3-二甲酰亚胺
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分类

  • {SNA} Active Esters/Additives, Alicyclic/Etch-Resistant Monomers, Chemical Biology, Chemical Synthesis, Coupling, Lithography Monomers, Micro/NanoElectronics, Monomers, Norbornene Monomers, Peptide Chemistry, Peptide Coupling, Polymer Science, Self Assembly & Contact Printing, Synthetic Reagents, 材料科学
  • {SNA} Active Esters/Additives, Alicyclic/Etch-Resistant Monomers, Chemical Biology, Chemical Synthesis, Coupling, Lithography Monomers, Materials Science, Micro/NanoElectronics, Peptide Chemistry, Peptide Coupling,
  • {SNA} Active Esters/Additi

产品应用

  • 多肽合成中的消旋抑制剂。有报道称其效果优于N-羟基琥珀酰亚胺(HOSu，NHS)

相关文献及参考

  • Beilstein: 21,V,10,188
  • Reagent for preparation of O-alkylhydroxylamines by O-alkylation and cleavage with hydrazine: Bull. Soc. Chim. Fr., 833 (1976). Compare N-Hydroxyphthalimide, A13862.
  • Reportedly superior to N-Hydroxysuccinimide, A10312 as a racemization suppressant in peptide synthesis: Chem. Pharm. Bull., 22, 1857 (1974); 26, 585 (1978). See Appendix 6.

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
WGK Germany3
GHS Symbol
Precautionary statements
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 阴凉干燥处保存。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Peptide Coupling - Peptide Chemistry
  5. Active Esters/Additives - Peptide Coupling

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