Pentafluorobenzoyl Chloride 五氟苯甲酰氯

CAS 2251-50-5 MFCD00000657

化学结构图

2251-50-5
SMILES: O=C(Cl)c1c(F)c(F)c(F)c(F)c1F

化学属性

Mol. FormulaC7ClF5O
Mol. Weight231
Boiling Point158-159
Refractive index1.4520 to 1.4540
Density1.601
TSCANo
Solubility分解
Flash PointNone
Appearance 无色液体。沸点158℃-159℃，折光率1.4536，比重1.601。
Stability对湿度敏感

别名和识别编码

Chemical NamePentafluorobenzoyl Chloride
CAS Number2251-50-5
Alfabeta NamePENTAFLUOROBENZOYLCHLORIDE
MDL NumberMFCD00000657
Synonym 2 2,3,4,5,6-PENTAFLUOROBENZOYL CHLORIDE 2,3,4,5,6-Pentafluor-benzoylchlorid 2,3,4,5,6-Pentafluoro-benzoyl chloride 2,3,4,5,6-Pentafluorobenzoic acid chloride 2,3,4,5,6-五氟苯甲酰氯 5-氟苯甲酰氯 PENTAFLUOROBENZOIC ACID CHLORIDE PERFLUOROBENZOYL CHLORIDE Pentafluorbenzoylchlorid Pentafluorobenzoic acid chloride, Perfluorobenzoyl chloride Perfluorbenzoylchlorid Perfluorobenzoyl Chloride Perfluorobenzoyl chloride pentafluorobenzoyl acetate pentafluorobenzoyl chloride 五氟苯甲酰氯 五氟苯甲酰氯 五氟苯酰氯
PubChem Substance ID75256
EC Number218-842-4
Beilstein Registry Number2054397
Reaxys-RN2054397
Chemical Name Translation五氟苯甲酰氯
InChIKeyMYHOHFDYWMPGJY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00115339
InChIInChI=1S/C7ClF5O/c8-7(14)1-2(9)4(11)6(13)5(12)3(1)10
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carbonyl chloride; 1fragment
  • {SNA} Acid Halides, Acylation Reagents, Aryl Fluorinated Building Blocks, Building Blocks, C7-C8, Carbonyl Compounds, Chemical Synthesis, Derivatization Reagents, Derivatization agents, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks, 分析/色谱, 分析试剂, 发光化合物及其检测, 生化试剂
  • {SNA} Acid Halides, Acylation Reagents, Analytical Reagents, Analytical/Chromatography, Aryl Fluorinated Building Blocks, Biochemicals and Reagents, Building Blo

产品应用

  • Pentafluorobenzoyl Chloride is a useful analytical reagent in the derivatization amphetamines as well as other primary amines.

相关文献及参考

  • Koster, E. et al.: Analyst, 127, 598 (2002);
  • Short: EINECS
  • Short: III/20b
  • Reagent for the preparation of derivatives of primary amines, etc. for GC. For monographs on GC reagents, see: D. R. Knapp, Handbook of Analytical Derivatisation Reactions, Wiley, N.Y. (1979); Handbook of Derivatives for Chromatography, 2nd ed., K. Blau and J. M. Halket, Eds., Wiley, Chichester (1993).

安全信息

Warnings LACHRYMATOR, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S8 Keep container dry 保持容器干燥；
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 3265 UN 3265 8/PG 2 UN3265
Storage condition Moisture Sensitive 2-8°C
Packing GroupII
Hazard Class8

其他信息

  • 海关编码:29163900
  • Hazard Note:Corrosive/Lachrymator
  • Sigma Aldrich:2251-50-5(sigmaaldrich)
  • F:10-19-21
  • 五氟苯甲酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0807 五氟苯甲酰氯 Pentafluorobenzoyl Chloride 5G 506元 2014/06/02 P0807 五氟苯甲酰氯 Pentafluorobenzoyl Chloride 25G 1510元 2010/06/21 147120050 五氟苯甲酰氯 Pentafluorobenzoyl chloride 98% 5 GR 648元
  • MOL 文件:2251-50-5.mol
  • MSDS 信息:2,3,4,5,6-Pentafluorobenzoyl chloride(2251-50-5).msds
  • TCI Shanghai:五氟苯甲酰氯 Pentafluorobenzoyl Chloride,>;98.0%(GC)(2251-50-5)
  • 敏感性:Lachrymatory
  • Acros Organics:五氟苯甲酰氯 Pentafluorobenzoyl chloride, 98%(2251-50-5)
  • 用途一:用作医药、农药、液晶材料中间体
  • Alfa Aesar:五氟苯酰氯,98+% Pentafluorobenzoyl chloride, 98%(2251-50-5)

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Luminescent Compounds/Detection - Biochemicals and Reagents
  4. Derivatization agents - Luminescent Compounds/Detection
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C7-C8 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents GC
  4. GC Derivatization Reagents, by Application
  5. Steroids
  1. Analytical & Chromatography 分析化学与色谱
  2. Gas Chromatography (GC) 气相色谱
  3. Derivatization Reagents
  4. GC Derivatization Reagents, by Application
  5. Steroids
  1. Acyl halide
  2. acyl chloride
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Luminescent Compounds/Detection
  4. Chemiluminescent compounds

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