Potassium perfluorooctanesulfonate 全氟辛基磺酸钾盐

CAS 2795-39-3 MFCD00066407

化学结构图

2795-39-3
SMILES: O=S(=O)([O-])C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.[K+]

化学属性

Mol. FormulaCF3(CF2)7SO3K
Mol. Weight538.22
Melting Point265-270
TSCAYes
Appearance 本品为白色或微黄色粉末。
Density0.77
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NamePerfluorooctanesulfonic acid potassium salt
CAS Number2795-39-3
Alfabeta NamePOTASSIUMPERFLUOROOCTANESULFONATE
MDL NumberMFCD00066407
Synonym ######## 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Heptadecafluoro-1-octanesulfonicacid,potassiumsalt 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-1-octanesulfonic acid 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-1-octanesulfonicacipota 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctane-1-sulfonic acid 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十七氟代-1-辛烷磺酸钾盐 1-Octanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro- 1-Octanesulfonicacid,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-,potassiumsalt 1-perfluorooctanesulfonic acid FC-80 FC-95 HEPTADECAFLUOROOCTANESULFONIC ACID POTASSIUM SALT PERFLUOROOCTANESULFONIC ACID PERFLUOROOCTANESULFONIC ACID POTASSIUM SALT PERFLUOROOCTANESULPHONIC ACID, POTASSIUM SALT PFOS compound PFOS perfluorooctanesu
Beilstein Registry Number3864579
EC Number220-527-1
PubChem Substance ID23669238
Chemical Name Translation全氟辛基磺酸钾盐
LabNetwork Molecule IDLN00120557
InChIInChI=1S/C8HF17O3S.K/c9-1(10,3(13,14)5(17,18)7(21,22)23)2(11,12)4(15,16)6(19,20)8(24,25)29(26,27)28;/h(H,26,27,28);/q;+1/p-1
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分类

  • Analytical Standards,
  • {SNA} Buildin
  • {SNA} Additional Standards, Analytical Standards, Chemical Class, Chemical Synthesis, Chromatography, Drinking Water, Environmental Standards, Fluoro, Fluorous Synthesis, Food & Beverage Standards, Food Residuals, Food and Cosmetic Component Standards, Halogenated, Organic Pollutant Standards, Perfluoro Compounds, Perfluorocarboxylates, Processing & Packaging Contaminant Standards, Rf-Tagged Building Blocks and Precursors, Specialty Synthesis, 分析/色谱
  • {SA} Analytical Standards, Analytical/Chromatography, Chemical Class, Chemical Synthesis, Chro

产品应用

  • Heptadecafluorooctanesulfonic Acid (PFOS) is a persistent environmental pollutant that may cause adverse health effects in humans.

相关文献及参考

  • Xu, L., et al.: Drug Metab. Dispos., 34, 1406 (2006),
  • Lau, C., et al.: Toxicol. Sci., 99, 366 (2007),
  • Paul, A., et al.: Environ. Sci. Technol., 43, 386 (2009),

安全信息

Warnings IRRITANT 危化品目录(2015) 危险化学品
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P263 Avoid contact during pregnancy/while nursing. 怀孕/哺乳期间避免接触。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P312
  • P301+P316
  • P301+P317
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P307+P311
  • P308+P313
  • P308+P316
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P317
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P337+P313
  • P337+P317
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSRG9701850
GHS Symbol
WGK Germany3
Signal word Warning
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H362 May cause harm to breast-fed children 可能对母乳喂养的婴儿造成伤害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Hazard Codes T,N Xn,N,C,Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Safety Statements
UN Number UN 2811 6.1/PG 3
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Packing GroupIII
Restrict -

其他信息

  • 全氟辛基磺酸钾价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0729 十七氟-1-辛烷磺酸钾 Potassium Heptadecafluoro-1-octanesulfonate 25G 1090元 2010/05/25 B23131 全氟辛烷磺酸钾, 98% Perfluorooctanesulfonic acid potassium salt, 98% 5g 981元 2010/05/25 B23131 全氟辛烷磺酸钾, 98% Perfluorooctanesulfonic acid potassium salt, 98% 25g 3528元
  • MOL 文件:2795-39-3.mol
  • Sigma Aldrich:2795-39-3(sigmaaldrich)
  • 上游原料:乙醇 --> 氢氟酸 --> 氧化钙 --> (1R,2R)-2-氨基-1-(4-硝基苯基)丙烷-1,3-二醇
  • 图谱信息:全氟辛基磺酸钾(2795-39-3)红外图谱(IR2) 全氟辛基磺酸钾(2795-39-3)红外图谱(IR1)
  • Alfa Aesar:全氟辛烷磺酸钾,98% Perfluorooctanesulfonic acid potassium salt, 98%(2795-39-3)
  • 用途二:本品作为铬雾抑制剂，在电镀铬时定量加入本品，电解时则形成一定厚度的细密泡沫层，有效的抑制酸雾放出。保护环境，节约铬酐。
  • TCI Shanghai:全氟辛基磺酸钾 Potassium Heptadecafluoro-1-octanesulfonate,>;98.0%(T)(2795-39-3)
  • 方法一:将无水氟化氢加入电解槽中，在15V左右进行电解干燥，当电流降到一定值后，加入辛基磺酸，控制电压4～15 V，电流强度0.1～2A，温度10～15 ℃，进行电化学氟化反应。定期从底部放出反应生成物，并补入原料直至极板钝化为止。反应生成物为辛基磺酸氟。精制后备用。 在洗盐釜中，预先加入95%乙醇和与乙醇等体积的去离子水，再加入一定的氢氧化钾，氧化钙，升温至70 ℃。然后，在搅拌下滴加计量的辛基磺酸氟。当pH值至7时，终止反应。趁热过滤。除去滤渣。滤液冷却，结晶，过滤，干燥后即为成品。
  • 用途一:本品系全氟阴离子表面活性剂
  • Hazard Note:Corrosive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  4. Rf-Tagged Building Blocks and Precursors - Fluorous Synthesis
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Food & Beverage Standards - Chromatography
  5. Food Residue Analysis - Food & Beverage Standards
  6. Perfluorocarboxylates - Food Residue Analysis
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonic/Sulfinic Acids 磺酸/亚磺酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonic/Sulfinic Acids 磺酸/亚磺酸
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Functional Group 官能团索引
  2. orthocarboxylic acid derivative
  1. Organo Fluorine
  2. Fluorine

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