trans-2,5-Dimethylpiperazine 反式-2,5-二甲基哌嗪

CAS 2815-34-1 MFCD00070516

化学结构图

2815-34-1
SMILES: C[C@H]1CN[C@H](C)CN1

化学属性

Mol. FormulaC6H14N2
Mol. Weight114
Boiling Point162-165
Melting Point115-118
Flash Point58°(136°F)
TSCANo
Density0.53
Solubility50 G/100 ML (20 ºC)
Appearance 反式-2,5-二甲基哌嗪(2815-34-1)为白色或淡黄色结晶体。熔点113-118℃, ; 沸点 ;162℃

别名和识别编码

Chemical Nametrans-2,5-Dimethylpiperazine
CAS Number2815-34-1
Alfabeta NameDIMETHYLPIPERAZINE TRANS25--,
MDL NumberMFCD00070516
PubChem Substance ID220672
EC Number203-409-4
Beilstein Registry Number79886
Reaxys-RN79886
Synonym 反式-2,5-二甲基哌嗪 (2S,5R)-2,5-DIMETHYL-PIPERAZINE 2,5-DIMETHYLPIPERAZINE 反式-2,3-二甲基哌嗪 TRANS-2,5-DIMETHYLPYRAZINE trans-2,5-Dimethylpiperazine,98% 反式-2,5-二甲基六氢吡嗪 (2S)-2β,5α-Dimethylpiperazine Trans-2,5-Dimethylpiperzine trans-1,2-dimethylpiperazine Piperazine, 2,5-dimethyl-, (2R,5S)- 反式2,5-二甲基哌嗪 TRANS-2,5-DIMETHYLPIPERAZINE 2,5-Dimethylpiperazine 反式-2,5-二甲基六氢对二嗪 反式二甲基哌嗪 2,5-二甲基哌嗪 trans-2,5-二甲基哌嗪 2,5-二甲基哌嗪(反式) 反2,5-二甲哌【口+井】
Chemical Name Translation反式-2,5-二甲基哌嗪
InChIKeyNSMWYRLQHIXVAP-OLQVQODUSA-P
LabNetwork Molecule IDLN04643922
InChIInChI=1S/C6H14N2/c1-5-3-8-6(2)4-7-5/h5-8H,3-4H2,1-2H3/t5-,6+
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分类

  • {SNA} Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Piperazines
  • Building Blocks, C4 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Piperazines

相关文献及参考

  • Aldrich MSDS 1 , 796:A / Corp MSDS 1 (1), 1409:B / FT-IR 1 (1), 372:C / FT-IR 2 (1), 580:C / FT-NMR 1 (1), 583:A / IR-Spectra (3), 220:G / IR-Spectra (2), 198:D / NMR-Reference 2 (1), 327:C / RegBook 1 (1), 393:C / Sax 6 , 1195 / Structure Index 1 , 56:A:6 / Vapor Phase 3 , 464:C
  • Beil. 23 ,19

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes F,Xn,C F,Xn
Hazard statements
  • H228 Flammable solid 易燃固体
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P302+P352+P312+P361+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
Signal word
UN Number
RTECSTL5950000
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R35 Causes severe burns 会导致严重灼伤
Packing GroupII
Hazard Class4.1/6.1
Storage condition Flammables area

其他信息

  • Alfa Aesar:反式-2,5-二甲基哌嗪,98% trans-2,5-Dimethylpiperazine, 98%(2815-34-1)
  • MSDS 信息:2,5-Dimethylpiperazine(2815-34-1).msds
  • 用途一:用作医药中间体
  • 检测方法:GC
  • TCI Shanghai:反-2,5-二甲基哌嗪 trans-2,5-Dimethylpiperazine,>;99.0%(GC)(T)(2815-34-1)
  • Sigma Aldrich:2815-34-1(sigmaaldrich)
  • 上游原料:乙醇 --> 氢氧化钠 --> 盐酸 --> 丙酮 --> 钯 --> 硼氢化钠 --> 溴化苄 --> 左旋酒石酸 --> 苦味酸 --> D-酒石酸 --> 2,5-二甲基吡嗪
  • 图谱信息:反式-2,5-二甲基哌嗪(2815-34-1)红外图谱(IR3) 反式-2,5-二甲基哌嗪(2815-34-1)核磁图( 13 CNMR) 反式-2,5-二甲基哌嗪(2815-34-1)红外图谱(IR1) 反式-2,5-二甲基哌嗪(2815-34-1)核磁图( 1 HNMR) 反式-2,5-二甲基哌嗪(2815-34-1)质谱(MS) 反式-2,5-二甲基哌嗪(2815-34-1)红外图谱(IR2)
  • Acros Organics:反式-2，5-二甲基哌嗪 trans-2,5-Dimethylpiperazine, 98%(2815-34-1)
  • MOL 文件:2815-34-1.mol
  • 反式-2,5-二甲基哌嗪价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0763 反-2,5-二甲基哌嗪 trans-2,5-Dimethylpiperazine 5G 707元 2014/06/02 D0763 反-2,5-二甲基哌嗪 trans-2,5-Dimethylpiperazine 25G 2150元 2010/06/21 116660050 反式-2,5-二甲基哌嗪 trans-2,5-Dimethylpiperazine 98% 5 GR 707元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Oxazolines/Oxazolidines 恶唑啉/恶唑烷
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperazines 哌嗪
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperazines 哌嗪
  5. C4 to C8 - Piperazines

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