4-Oxo-Tempo 4-氧-TEMPO

CAS 2896-70-0 MFCD00006187

化学结构图

2896-70-0
SMILES: CC1(C)CC(=O)CC(C)(C)N1[O]

化学属性

Mol. FormulaC9H16NO2?
Mol. Weight170.23
Melting Point33-38 °C
TSCAYes
Boiling Point299.88 °C at 760 mmHg

别名和识别编码

Chemical Name4-Oxo-Tempo
Synonym Tempone {LY} Tempone {} {LY} Tempone {} {} {LY} Tempone {} {} {} {LY} Tempone {} {} {} {} {LY} Tempone {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tempone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00006187
PubChem Substance ID520789
CAS Number2896-70-0
EC Number220-778-7
Reaxys-RN1818579
Beilstein Registry Number1818579
Chemical Name Translation4-氧-TEMPO
LabNetwork Molecule IDLN01290579
InChIInChI=1S/C9H16NO2/c1-8(2)5-7(11)6-9(3,4)10(8)12/h5-6H2,1-4H3
Canonical SMILES[O]N1C(C)(C)CC(CC1(C)C)=O
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Electron Spin Resonance (ESR/EPR) Spectroscopy, Radical Chemistry, Spectroscopy, Spin Labels, Stable Radicals, Synthetic Reagents, TEMPO Derivatives
  • {SNA} Chemical Synthesis, Electron Spin Resonance (ESR/EPR) Spectroscopy, Radical Chemistry, Spectroscopy, Spin Labels,
  • Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Electron Spin Resonance (ESR/EPR) Spectroscopy, Radical Chemistry, Spectroscopy, Spin Labels, Stable Radicals, Synthetic Reagents, TEMPO Derivatives
  • {SNA} Chemical Synthesis,

相关文献及参考

  • 1. G. Salinas and M. Aguilar-Martinez, , Electrochemical Characterization of Stable Nitroxyl Radical, Intermediaries in the Synthesis of 3-Methacryloylamin-PROXYL ECS Transactions 36 , 483-490, (2011)
  • 2. C. A. Shaw, et al., , Differential susceptibility to nitric oxide-evoked apoptosis in human inflammatory cells Free Radic. Biol. Med. 50 , 93-101, (2011)
  • 3. C. L. Hartwig, et al., , Investigating the Antimalarial Action of 1,2,4-Trioxolanes with Fluorescent Chemical Probes J. Med. Chem. 54 , 8207-8213, (2011)
  • 4. M. Turke and M. Bennati,, Saturation factor of nitroxide radicals in liquid DNP by pulsed ELDOR experiments Phys. Chem. Chem. Phys. 13 , 3630-3633, (2011)
  • 5. L. Tebben and A. Studer, , Nitroxides: Applications in Synthesis and in Polymer Chemistry Angew. Chem. Int. Ed. Engl. 50 , 5034-5068, (2011)
  • Beil. 21 ,6,544
  • FT-IR 2 (1), 722:D / FT-IR 1 (1), 462:A / IR-Spectra (3), 273:D / IR-Spectra (2), 244:D / RegBook 1 (1), 499:N / Sigma FT-IR 1 (2), 816:A / Structure Index 1 , 71:C:7
  • Reviews: Synthesis and reactions of stable nitroxyl radicals: Synthesis, 190, 401 (1971); Advances in the chemistry of nitroxide spin labels: Chem. Rev., 78, 37 (1978); Recent advances in the chemistry of nitroxides and their applications in spin labelling: J. Sci. Ind. Res., 54, 623 (1995).
  • Reviews: Synthesis and reactions of stable nitroxyl radicals: Synthesis, 190, 401 (1971); Advances in the chemistry of nitroxide spin labels: Chem. Rev., 78, 37 (1978); Recent advances in the chemistry of nitroxides and their applications in spin labelling: J. Sci. Ind. Res., 54, 623 (1995).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSTN9200000
Storage condition 2-8°C {LY} 2-8°C <0°C <;0 {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupIII
UN Number 3077
Hazard Codes 9 
TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 10 mg/L
REFERENCE :
   NTRSDC Nutrition Research.  (Pergamon Press Inc., Maxwell House, Fairview
   Park, Elmsford, NY 10523) V.1-   1981-  Volume(issue)/page/year: 4,989,1984

Hazard Class9

其他信息

  • 图谱信息:4-氧-2,2,6,6-四甲基哌啶-1-氧自由基(2896-70-0)红外图谱(IR1)
  • MSDS 信息:4-Oxo-TEMPO(2896-70-0).msds
  • MOL 文件:2896-70-0.mol
  • 用途一:该品对丙烯酸酯类、甲基丙烯酸酯类、丙烯酸、丙烯腈、苯乙烯、丁二烯有较好的阻聚效果。其阻聚性能优于酚类、芳胺类、醚类、醌类和硝基化合物等阻聚剂。
  • 4-氧-2,2,6,6-四甲基哌啶-1-氧自由基价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 O0266 4-氧代-2,2,6,6-四甲基哌啶 1-氧基自由基 4-Oxo-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical 5G 810元 2014/06/02 O0266 4-氧代-2,2,6,6-四甲基哌啶 1-氧基自由基 4-Oxo-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical 25G 2770元 2010/06/21 176860050 4-氧-2,2,6,6-四甲基哌啶-1-氧自由基 4-Oxo-2,2,6,6-tetramethylpiperidinooxy 95%, free radical 5 GR 2037元
  • Acros Organics:4-氧代-2，2,6，6-四甲基哌啶 4-Oxo-2,2,6,6-tetramethylpiperidinooxy, free radical, 95%(2896-70-0)
  • Alfa Aesar:4-羰基-四甲基哌啶氧自由基,96% 4-Oxo-TEMPO, free radical, 96%(2896-70-0)
  • TCI Shanghai:4-氧代-2,2,6,6-四甲基哌啶-1-氧基自由基 4-Oxo-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical,>;95.0%(GC)(T)(2896-70-0)
  • Sigma Aldrich:2896-70-0(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Homopiperidines 同哌啶
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperidines 哌啶
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Spectroscopy - Analytical Reagents
  4. Electron Spin Resonance (ESR/EPR) Spectroscopy - Spectroscopy
  5. Spin Labels - Electron Spin Resonance (ESR/EPR) Spectroscopy
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals - Radical Chemistry
  5. TEMPO Derivatives - Stable Radicals
  1. Analytical & Chromatography 分析化学与色谱
  2. ESR Spectrometry
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals
  5. Others

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