D-alanine 丙氨酸或者丙氨酸乙酯丙氨酸(LDL)(D-丙氨酸)

CAS 338-69-2 MFCD00008077

化学结构图

338-69-2
SMILES: C[C@@H](N)C(=O)O

化学属性

Mol. FormulaC3H7NO2
Mol. Weight89.09
Melting Point291°C
Density1.161
TSCAYes
Solubility155 G/L (20 ºC)
Appearance 25 无色结晶状物质；无异臭，味甜；易溶于水，微溶于乙醇，不溶于丙酮和乙醚；分解点为297℃；比旋光度[α] -14.6°(0.5-2.0 mg/ml，5 mol/L HCl)。 D -1.8°(0.5-2.0 mg/ml，H2O)，[α]
Refractive index-14 ° (C=2, 6mol/L HCl)
Boiling Point212.9±23.0 °C at 760 mmHg

别名和识别编码

Chemical NameD-Alanine
CAS Number338-69-2
Alfabeta NameALANINE D-
MDL NumberMFCD00008077
Synonym D-Alanine {LY} D-Alanine L Alanine L-Alanine L-Isomer Alanine {} {LY} D-Alanine {} {} {LY} D-Alanine {} {} {} {LY} D-Alanine {} {} {} {} {LY} D-Alanine {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Alanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Alanine
Beilstein Registry Number1720249
PubChem Substance ID71080
EC Number206-418-1
Reaxys-RN1720249
Merck Number14,204
Chemical Name Translation丙氨酸或者丙氨酸乙酯丙氨酸(LDL)(D-丙氨酸)
LabNetwork Molecule IDLN00007123
InChIInChI=1S/C3H7NO2/c1-2(4)3(5)6/h2H,4H2,1H3,(H,5,6)/t2-/m1/s1
Canonical SMILESN[C@@H](C(O)=O)C
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分类

  • {Chemicalbook} 生物化学品: 生化试剂: 氨基酸及其衍生物
  • {uni_hamburg} no charge; carboxylic acid; chiral; 1fragment
  • {SNA} Alanine, Amino Acids, Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry, 生化试剂
  • {SNA} Alanine, Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry
  • {SNA} Alanine, Amino Acid Derivatives, Amino Acids, Chemical Biology, Chemical Synthesis, Peptide Chemistry, 生化试剂
  • Alanine, Amino Acid Derivatives, Amino Acids, Biochemicals and Reagents, Chemical Biology, Chemical Synthesis,

相关文献及参考

  • [2]. Saitoh T, et al. A novel antagonist, phenylbenzene omega-phosphono-alpha-amino acid, for strychnine-sensitive glycine receptors in the rat spinal cord. Br J Pharmacol. 1994 Sep;113(1):165-70.
  • Beilstein:4(4)2481
  • Short: EINECS
  • Short: III/5a
  • Short: IV/1b
  • [1]. Schmieden V, et al. Pharmacology of the inhibitory glycine receptor: agonist and antagonist actions of amino acids and piperidine carboxylic acid compounds. Mol Pharmacol. 1995 Nov;48(5):919-27.
  • [1]. Schmieden V, et al. Pharmacology of the inhibitory glycine receptor: agonist and antagonist actions of amino acids and piperidine carboxylic acid compounds. Mol Pharmacol. 1995 Nov;48(5):919-27.
  • [2]. Saitoh T, et al. A novel antagonist, phenylbenzene omega-phosphono-alpha-amino acid, for strychnine-sensitive glycine receptors in the rat spinal cord. Br J Pharmacol. 1994 Sep;113(1):165-70.

安全信息

Warnings IRRITANT
WGK Germany1
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P317
  • P337+P317
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition 2-8°C {LY} 2-8°C Store at RT. {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • 用途一:用于合成新型甜味剂及某些手性药物中间体的原料
  • MSDS 信息:D-Alanine(338-69-2).msds
  • Acros Organics:D-丙氨酸 D-Alanine, 99+%(338-69-2)
  • 图谱信息:D-丙氨酸(338-69-2)质谱(MS) D-丙氨酸(338-69-2)红外图谱(IR2) D-丙氨酸(338-69-2)红外图谱(IR1) D-丙氨酸(338-69-2)核磁图( 1 HNMR) D-丙氨酸(338-69-2)Raman光谱 D-丙氨酸(338-69-2)核磁图( 13 CNMR)
  • 下游产品:甘氨酸 --> 依那普利 --> DL-丙氨酸 --> 咪达普利 --> 胆红素 --> D-环丝氨酸 --> L-天门冬酰-D-丙氨酰胺 --> BOC-D-丙氨酸 --> 阿力甜
  • 用途二:用于生化研究。
  • 上游原料:N-乙酰-DL-丙氨酸
  • Alfa Aesar:D-丙氨酸,99% D-Alanine, 99%(338-69-2)
  • Sigma Aldrich:338-69-2(sigmaaldrich)
  • 方法一:以N-乙酰-DL-丙氨酸为原料，经酰化酶拆分除去L-丙氨酸后，盐酸水解，重结晶精制而得。
  • TCI Shanghai:D-丙氨酸 D-Alanine,>;98.0%(T)(338-69-2)
  • D-丙氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xp620003 D-丙氨酸;D-初油氨基酸;D-丝析氨酸 10g/瓶 54元 2011/08/23 62001231 D-α-丙氨酸 1g 26元 2011/04/16 A0177 D-丙氨酸 D-Alanine 5G 273元
  • 参考质量标准:比旋光度[α] 25 D -12.5°--14.5°(0.5-2.0 mg/ml，5mol/L HCl)；纸层析合格。
  • MOL 文件:338-69-2.mol
  • 比旋光度:-14.5 ° (c=10, 6N HCl)

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Alanine - Amino Acid Derivatives
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Amino Acids
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Albumins and Transport Proteins
  4. Albumin
  1. Medical Research Areas
  2. Metabolism
  3. Endogenous Metabolite  (内源性代谢物)

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