(1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-(+)-1,2-二苯基乙二胺

CAS 35132-20-8 MFCD00082769

化学结构图

35132-20-8
SMILES: N[C@H](c1ccccc1)[C@H](N)c1ccccc1

化学属性

Mol. FormulaC14H16N2
Mol. Weight212.30
Melting Point79-83
TSCANo
Density1.106
Appearance 无色针状晶体，无臭，不溶于水，易溶于甲醇、乙醇，在空气中易氧化。
Stability对空气敏感

别名和识别编码

Chemical Name(1R,2R)-(+)-1,2-Diphenylethylenediamine
Synonym (1R,2R)- DPEDA (1R,2R)-(+)-1,2-Diamino-1,2-diphenylethane (1R,2R)-(+)-1,2-二氨基-1,2-二苯基乙烷 (1R,2R)-(+)-1,2-二苯基-1,2-乙二胺 (1R,2R)-DPEN
Beilstein Registry Number2369988
PubChem Substance ID87568616
CAS Number35132-20-8
MDL NumberMFCD00082769
Reaxys-RN3201645
EC Number250-023-7
Chemical Name Translation(1R,2R)-(+)-1,2-二苯基乙二胺
LabNetwork Molecule IDLN00008832
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分类

  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyamines
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyamines

相关文献及参考

  • Chiral solvation agent for determination of enantiomeric excess of chiral acids by NMR.
  • In combination with various Lewis acids, forms a number of catalyst systems for asymmetric reactions including Diels-Alder, allylation and aldol reactions: Angew. Chem. Int. Ed., 30, 455 (1991). For use in enantioselective catalytic Diels-Alder reactions, see: J. Am. Chem. Soc., 111, 5493 (1989); Org. Synth. Coll., 9, 67 (1998).

安全信息

WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi,C Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
UN Number UN3259
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 对空气敏感，密封保存。 Air Sensitive
Packing GroupIII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Amides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Polyamines - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Polyamines - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphonic/Phosphinic Acids 膦酸
  1. DPEN
  2. Nitrogen
  1. Ligands
  2. Nitrogen

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