Boron Trifluoride Methyl Etherate 三氟化硼二甲醚

CAS 353-42-4 MFCD00013192

化学结构图

353-42-4
SMILES:

化学属性

Mol. FormulaC2H6BF3O
Mol. Weight114
Refractive indexn20/D 1.308(lit.)
Autoignition Point455 °F
Boiling Point126-127
Density1.239
Melting Point-15
Flash Point62 ºC
Solubility起反应

别名和识别编码

Chemical NameBoron Trifluoride Methyl Etherate
Synonym Bortrifluorid-Dimethylether-Komplex Boron fluoride (BF3), compd. with methyl ether (1:1) dimethylether-borontrifluoride(1:1)complex Borane, trifluoro-, compd. with oxybis[methane] (1:1) 三氟化硼二甲醚 Methane, oxybis-, boron complex Dimethyl ether--boron trifluoride BORON TRIFLUORIDE METHYL Boron trifluoride compd. with methyl ether 三氟化硼甲醚 BORON TRIFLUORIDE-METHYL ETHER COMPLEX borontrifluoride-methylethercomplexabout60% BORON TRIFLUORIDE METHYL ETHERATE dimethyl ether-boron trifluoride(1:1)complex Dimethylether-borontrifluoride(1:1)-complex Borane, trifluoro-, compd. with oxybis(methane borontrifluoridecompoundwith BORON TRIFLUORIDE-METHYL dimethyl ether--boron trifluoride Boron
MDL NumberMFCD00013192
CAS Number353-42-4
Beilstein Registry Number3613739
PubChem Substance ID2724165
EC Number206-532-1
Chemical Name Translation三氟化硼二甲醚
Wiswesser Line Notation1O1 &&B-F3
InChIKeyFOWZWMGLMYVYDH-UHFFFAOYSA-N
LabNetwork Molecule IDLN01808725
InChIInChI=1S/C2H6BF3O/c1-7(2)3(4,5)6/h1-2H3
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分类

  • {SNA} Acids, Acids & Bases, Boron, Boron Catalysts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Boron, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Synthetic Reagents
  • {SNA} Acids,

产品应用

  • 本产品是用作很多有机反应的有效催化剂, 稳定性好, 可作为烷基化的催化剂

相关文献及参考

  • Short: EINECS
  • Short: III/35A
  • Short: IV/20A
  • Short: IV/20B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H332 Harmful if inhaled 吸入有害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSED8400000
Precautionary statements
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P231+P232
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P335+P334
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes 4.3 F,C F;T;C
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R48/23
UN Number 2965
Packing GroupI
Storage condition water-free area
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 50 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

其他信息

  • 毒害物质数据:353-42-4(Hazardous Substances Data)
  • EPA化学物质信息:Boron, trifluoro[oxybis[methane]]-, (T-4)-(353-42-4)
  • PackingGroup:I
  • RTECS号:ED8400000
  • HazardClass:4.3
  • 三氟化硼-二甲醚络合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 204060500 三氟化硼-二甲醚络合物 Boron trifluoride dimethyl etherate 50 ML 492元 2010/06/21 204062500 三氟化硼-二甲醚络合物 Boron trifluoride dimethyl etherate 250 ML 1627元
  • F:10
  • MOL 文件:353-42-4.mol
  • 用途:是很多有机反应的有效催化剂,稳定性较好,可作为烷基化的催化剂

系列性分类


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