2,6-Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine 2,6-双[(3AR,8AS)-(+)-8H-茚并[1,2-D]噁唑啉-2-基)吡啶

CAS 357209-32-6 MFCD09265074

化学结构图

357209-32-6
SMILES: C1[C@@H]2OC(=N[C@@H]2C2C=CC=CC=21)C1C=CC=C(N=1)C1=N[C@H]2[C@H](CC3C=CC=CC=32)O1

化学属性

Mol. FormulaC25H19N3O2
Mol. Weight393.44
Melting Point266-284
Appearance white to light yellow pwdr.
Stabilitystore cold

别名和识别编码

Chemical Name2,6-Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine
Synonym 2,6-双[(3aR,8aS)-(+)-8H-茚并[1,2-d]噁唑啉-2-基)吡啶 (3aR,3′aR,8aS,8′aS)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑 (3aR,8aS)-in-pybox (3aR,3′aR,8aS,8′aS)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑 (3aR,8aS)-in-pybox
MDL NumberMFCD09265074
PubChem Substance ID24885191
CAS Number357209-32-6
Chemical Name Translation2,6-双[(3AR,8AS)-(+)-8H-茚并[1,2-D]噁唑啉-2-基)吡啶
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX

相关文献及参考

  • 1. Li, L.; et al., Lewis acid-catalyzed formal [3+2] cycloadditions of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage Chem. Commun. 47 , 5049-5051, (2011)
  • 2. Zhao, J.-F.; et al., In(III)-pybox complex catalyzed enantioselective Mukaiyama aldol reactions between polymeric or hydrated glyoxylates and enol silanes derived from aryl ketones Chem. Sci. 2 , 349-352, (2011)
  • 3. Zhao, J.-F.; et al., Significant counterion effect of the In(III)-pybox complex in highly enantioselective carbonyl-ene reactions of ethyl glyoxylate Tetrahedron Lett. 51 , 5649-5652, (2010)
  • 4. Wang, J.; et al., Copper(I)-catalyzed asymmetric addition of terminal alkynes to β-imino esters: an efficient and direct method in the synthesis of chiral β3-alkynyl β2,2-dimethyl amino acid derivatives Adv. Synth. Catal. 351 , 1250-1254, (2009)
  • 5. Shao, Z.; et al., Enantioselective, copper(I)-catalyzed three-component reaction for the synthesis of β,γ-alkynyl α-amino acid derivatives Tetrahedron Asymmetry 20 , 225-229, (2009)
  • 6. Sibi, M. P.; et al., Exo- and enantioselective Diels-Alder reactions: pyrazolidinone auxiliaries as a means to enhanced exo selectivity Synlett , 2655-2658, (2008)
  • 7. Smith, S. W.; Fu, G. C. , Nickel-Catalyzed Asymmetric Cross-Couplings of Racemic Propargylic Halides with Arylzinc Reagents J. Am. Chem. Soc. 130 , 12645-12647, (2008)

安全信息

WGK Germany3
Hazard statements
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
GHS Symbol
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338

系列性分类


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