N-Boc-Hydroxylamine N-羟基氨基甲酸叔丁酯

CAS 36016-38-3 MFCD00002107

化学结构图

36016-38-3
SMILES: CC(C)(C)OC(=O)NO

化学属性

Mol. FormulaC5H11NO3
Mol. Weight133.15
Melting Point53-55°C
TSCANo
Density1.422
Boiling Point250.4°C at 760 mmHg

别名和识别编码

Chemical NameN-Boc-Hydroxylamine
CAS Number36016-38-3
Alfabeta NameBUTYLHYDROXYCARBAMATE TERTN--
MDL NumberMFCD00002107
Synonym N-tert-Butoxycarbonylhydroxylamine {LY} N-tert-Butoxycarbonylhydroxylamine {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-tert-Butoxycarbonylhydroxyl
PubChem Substance ID87571206
Beilstein Registry Number1756546
EC Number252-836-2
Reaxys-RN1756546
Chemical Name TranslationN-羟基氨基甲酸叔丁酯
InChIKeyDRDVJQOGFWAVLH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00221916
Canonical SMILESONC(=O)OC(C)(C)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Protected Amines

相关文献及参考

  • Precursor of O-substituted hydroxylamines, including the unstable O-acyl and O-sulfonylhydroxylamines which, having a good leaving group on nitrogen, are powerful aminating agents: J. Am. Chem. Soc., 82, 3133 (1960); Tetrahedron, 29, 1063 (1973); Synthesis, 140 (1972). For a review of O-mesitylenesulfonylhydroxylamine and related compounds, see: Synthesis, 1 (1977).

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。

系列性分类


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