4-Isothiocyanato-2,2,6,6-Tetramethylpiperidine 1-Oxyl 4-异硫氰基-2,2,6,6-四甲基哌啶-1-氧基

CAS 36410-81-8 MFCD00010109

化学结构图

36410-81-8
SMILES: CC1(C)CC(CC(C)(C)N1[O])N=C=S |^1:10|

化学属性

Mol. FormulaC10H17N2OS
Mol. Weight213.32
Melting Point126.0 to 130.0 deg-C

别名和识别编码

Chemical Name4-Isothiocyanato-2,2,6,6-Tetramethylpiperidine 1-Oxyl
Synonym 4-异硫氰基-2,2,6,6-四甲基哌啶1-氧自由基 4-异硫氰酰基-2,2,6,6-四甲基-1-哌啶氮氧自由基 4-异硫氰酰基-TEMPO 4-异硫氰基-TEMPO
CAS Number36410-81-8
PubChem Substance ID87571835
Beilstein Registry Number4421977
MDL NumberMFCD00010109
Chemical Name Translation4-异硫氰基-2,2,6,6-四甲基哌啶-1-氧基
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分类

  • {SA} Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents HPLC, Electron Spin Resonance (ESR/EPR) Spectroscopy, Radical Chemistry, Spectroscopy, Spin Labels, Stable Radicals, Synthetic Reagents,
  • Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents HPLC, Electron Spin Resonance (ESR/EPR) Spectroscopy, Radical Chemistry, Spectroscopy, Spin Labels, Stable Radicals, Synthetic Reagents, TEMPO Derivatives, UV-VIS

相关文献及参考

  • 1. Y. Chen et al., Anticancer drugs part III: New spin labelled derivatives of podophyllotoxin Curr. Sci. 59 , 517-518, (1990)

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Warning
Storage condition <;0 <0°C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Spectroscopy - Analytical Reagents
  4. Electron Spin Resonance (ESR/EPR) Spectroscopy - Spectroscopy
  5. Spin Labels - Electron Spin Resonance (ESR/EPR) Spectroscopy
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Radical Chemistry - Synthetic Reagents
  4. Stable Radicals - Radical Chemistry
  5. TEMPO Derivatives - Stable Radicals
  1. Analytical & Chromatography 分析化学与色谱
  2. ESR Spectrometry
  1. Functional Group 官能团索引
  2. hydroxylamine
  1. Functional Group 官能团索引
  2. isothiocyanate

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