Diethyl hexafluoroglutarate 2,2,3,3,4,4-六氟戊二酸二乙酯

CAS 424-40-8 MFCD00015156

化学结构图

424-40-8
SMILES: CCOC(=O)C(F)(F)C(F)(F)C(F)(F)C(=O)OCC

化学属性

Mol. FormulaC9H10F6O4
Mol. Weight296.17 g/mol
Boiling Point75 °C at 760 mmHg
Density1.365
Refractive index1.3600 to 1.3620
TSCAYes
Flash Point87°C(lit.)

别名和识别编码

Chemical NameDiethyl hexafluoroglutarate
CAS Number424-40-8
Alfabeta NameDIETHYLHEXAFLUOROGLUTARATE
MDL NumberMFCD00015156
Synonym Diethyl 2,2,3,3,4,4-Hexafluoropentanedioate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number207-035-2
Beilstein Registry Number1804802
Chemical Name Translation2,2,3,3,4,4-六氟戊二酸二乙酯
Reaxys-RN1804802
PubChem Substance ID9874
InChIKeyMSDPXVBLFJODJO-UHFFFAOYSA-N
LabNetwork Molecule IDLN00115351
InChIInChI=1S/C9H10F6O4/c1-3-18-5(16)7(10,11)9(14,15)8(12,13)6(17)19-4-2/h3-4H2,1-2H3
Canonical SMILESCCOC(=O)C(C(C(C(=O)OCC)(F)F)(F)F)(F)F
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安全信息

Warnings IRRITANT
RTECSMA3750500
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20 Harmful by inhalation 吸入有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Hazard Codes C
Signal word
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H330 Fatal if inhaled 吸入致命
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P317
  • P301+P330+P331
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P302+P361+P354
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1300 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,53,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,53,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,53,1982

Storage condition

其他信息

  • TCI Shanghai:2,2,3,3,4,4-六氟戊二酸二乙酯 2,2,3,3,4,4-Hexafluoropentanedioic Acid Diethyl Ester,>;98.0%(GC)(424-40-8)
  • 六氟戊二酸二乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0744 2,2,3,3,4,4-六氟戊二酸二乙酯 2,2,3,3,4,4-Hexafluoropentanedioic Acid Diethyl Ester 1G 319元 2010/05/25 B22428 六氟戊二酸二乙酯, 97% Diethyl hexafluoroglutarate, 97% 5g 1526元 2010/05/25 B22428 六氟戊二酸二乙酯, 97% Diethyl hexafluoroglutarate, 97% 25g 5894元
  • 六氟戊二酸二乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 H0744 2,2,3,3,4,4-六氟戊二酸二乙酯 2,2,3,3,4,4-Hexafluoropentanedioic Acid Diethyl Ester 1G 411元 2010/05/25 B22428 六氟戊二酸二乙酯, 97% Diethyl hexafluoroglutarate, 97% 5g 1526元 2010/05/25 B22428 六氟戊二酸二乙酯, 97% Diethyl hexafluoroglutarate, 97% 25g 5894元
  • Hazard Note:Corrosive
  • MOL 文件:424-40-8.mol
  • Alfa Aesar:六氟戊二酸二乙酯,97% Diethyl hexafluoroglutarate, 97%(424-40-8)
  • 图谱信息:六氟戊二酸二乙酯(424-40-8)核磁图( 13 CNMR) 六氟戊二酸二乙酯(424-40-8)核磁图( 1 HNMR) 六氟戊二酸二乙酯(424-40-8)红外图谱(IR1) 六氟戊二酸二乙酯(424-40-8)质谱(MS)

系列性分类