dimethyl dicarbonate 二烷酸二甲酯

CAS 4525-33-1 MFCD00008419

化学结构图

4525-33-1
SMILES: COC(=O)OC(=O)OC

化学属性

Mol. FormulaC4H6O5
Mol. Weight134.09
Refractive indexn20/D 1.392(lit.)
Boiling Point45-46 °C at 5 mmHg
Density1.25 g/mL at 25 °C(lit.)
Melting Point15-17 °C

别名和识别编码

Chemical Namedimethyl dicarbonate
Synonym Dimethyl dicarbonate {LY} Dimethyl dicarbonate {} {LY} Dimethyl dicarbonate {} {} {LY} Dimethyl dicarbonate {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl dicarbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number4525-33-1
PubChem Substance ID24893938
EC Number224-859-8
Beilstein Registry Number956715
MDL NumberMFCD00008419
Chemical Name Translation二烷酸二甲酯
LabNetwork Molecule IDLN00196660
Canonical SMILESCOC(OC(OC)=O)=O
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分类

  • {SA} Building Blocks, Carbonates, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • {SNA} A to C, Acetate kinase, Biochemicals and Reagents, D to K, Enzyme Inhibitors, Enzyme Inhibitors by E
  • {SNA} A to C, Acetate kinase, D to K, Enzyme Inhibitors, Enzyme Inhibitors by Enzyme, Glutamic Decarboxylase, L-, 生化试剂, 酶、抑制剂和底物
  • {SNA} A to C, Acetate kinase, Biochemicals and Reagents, D to K, Enzyme Inhibitors, Enzyme Inhibitors by Enzyme, Enzymes, Inhibitors, and Substrates, Gl

产品应用

  • A histidine methylator.

相关文献及参考

  • 1. Cheng, K.C., and Nowak T., A histidine residue at the active site of avian liver phosphoenolpyruvate carboxykinase J. Biol. Chem. 264 , 19666-19676, (1989) 摘要
  • Beil. 3 ,IV,17
  • Corp MSDS 1 (1), 1414:C / FT-NMR 1 (1), 929:B / RegBook 1 (1), 695:E / Structure Index 1 , 105:A:6 / Vapor Phase 3 , 634:B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
  • H302+H312
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T
RTECSHT0362500
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
  • S18 Handle and open container with care 小心搬运和开启容器；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R23 Toxic by inhalation 吸入有毒
Storage condition 2-8°C {LY} 2-8°C Store at room temperature room temp {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2- 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 711 mg/m3/4H
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0545284

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carbonates - Carbonyl Compounds
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Enzymes, Inhibitors, and Substrates - Biochemicals and Reagents
  4. Enzyme Inhibitors - Enzymes, Inhibitors, and Substrates
  5. Enzyme Inhibitors by Enzyme - Enzyme Inhibitors
  6. A to C - Enzyme Inhibitors by Enzyme
  7. Acetate kinase - A to C

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