• 原料直供
• 试剂商城
• 直接询价

分类

• Metabolites & Impurities,
• {SNA} Chemical Synthesis, Coupling, Phosgene Derivatives, Synthetic Reagents
• Aliphatics
• {Chemicalbook} 农药中间体: 杀螨剂中间体
• {uni_hamburg} no charge; 1fragment

产品应用

• Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000).

相关文献及参考

• Siegel, M.: Pest. Biochem. Physiol., 1, 234 (1971); Schwack, W.: Chemosphere, 16, 127 (1987);
• Short: II/14a Title: Molecular Constants: Diamagnetic Molecules Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/14a Page: 1-788 Year: 1982 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-11365-7 ISBN: 978-3-540-11365-2 Internet Resource: DOI:10.1007/b19966 RefComment: 196 figs., XI
• Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
• Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-54

安全信息

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 929 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku,"
   Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu
   Praha, Czechoslovakia, 1972  Volume(issue)/page/year: -,13,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04557

其他信息

• MOL 文件:463-71-8.mol
• 硫光气价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1320 硫光气 Thiophosgene 100G 2730元 2014/06/02 T1320 硫光气 Thiophosgene 25G 875元 2010/06/21 151641000 硫光气 Thiophosgene 97% 100 GR 2130元
• 灭火剂:砂土, 二氧化碳
• 方法一:硫光气是由全氯甲硫醇还原制得。 在全氯甲硫醇、四氯乙烷和水的混合物中添加碘化钾，搅拌，于室温下通入二氧化硫，反应中自动升温，调节通气量，保持温度在50～70℃。当反应液温度不再上升、二氧化硫不再明显吸收时停止通气，冷却静置，分取有机层进行分馏，收集76℃以下馏分得硫光气。
• 刺激数据:皮肤-兔子 500 毫克/24小时 中度; 眼睛-兔子 0.05 毫克/24小时 重度
• 类别:有毒物品
• 外观性质:红色液体，有刺激性气味。
• 下游产品:异硫氰酸荧光素酯 --> 1-(1,3-二甲基-1H-吡唑-5-基)乙酮 --> 3-异硫氰酸基-1,5-二甲基-1H-吡唑 --> 5-溴-6-异硫氰酸喹喔啉 --> 1,3-苯并二唑-5-基异硫氰酸酯 --> 4-硝基-4'-异硫氰基二苯胺 --> 4-(1H-吡唑-1-基)苯基异硫氰酸酯 --> 4-苯氧基-2,6-二异丙基苯硫代异氰酸酯 --> 对苯二异硫氰酸酯 --> 二吡啶硫碳酸酯 --> 4-羧基苯基异硫氰酸酯 --> 3-氯-2-甲基苯基异硫氰酸酯 --> 2-乙氧基苯基异硫氰酸酯 --> 2,3-二氢-1,4-苯并二氧-6-基异硫氰酸酯 --> 3,5-二甲基苯基异硫氰酸酯 --> 2-氯-4-甲基苯基异硫氰酸酯 --> 4-氯-2-甲基苯基异硫氰酸酯 --> 3,5-二甲氧基苯基异硫氰酸酯
• 急性毒性:口服-大鼠 LD50: 929 毫克/公斤; 吸入-小鼠 LC50: 0.37 克/立方米
• 储运特性:库房通风低温干燥; 与强酸, 食品分开储运
• 方法二:由全氯甲硫醇还原消除而得。在全氯甲硫醇、四氯乙烷和水和混合物中添加碘化钾，搅拌，于室温下通入二氧化硫，反应中自动升温，调节通气量，保持温度在50-70℃。当反应液温度不再上升，二氧化硫不再明显吸收时停止通气。冷却静置，分取有机层进行分馏，收集76℃以下馏分，得硫光气。
• 可燃性危险特性:遇酸分解有毒, 易燃硫化氢及氯化氢气体; 水中缓慢分解以上气体
• 用途一:硫光气是制备杀螨剂丁醚脲的中间体，也是制备硫代氨基甲酸酯类杀虫剂和除草剂的重要中间体。
• 上游原料:碘化钾 --> 二氧化硫 --> 1,1,2,2-四氯乙烷 --> 全氯甲硫醇
• 蒸气密度:4 (vs air)
• 毒性分级:高毒
• MSDS 信息:二氯硫化碳(463-71-8).msds
• TCI Shanghai:硫光气 Thiophosgene,>;95.0%(GC)(463-71-8)
• 用途二:用于有机合成。
• Acros Organics:硫光气 Thiophosgene, 97%(463-71-8)
• F:19-21
• Sigma Aldrich:463-71-8(sigmaaldrich)