(+)-Borneol (+)-冰片

CAS 464-43-7 MFCD00066427

化学结构图

464-43-7
SMILES:

化学属性

Mol. FormulaC10H18O
Mol. Weight154
Melting Point206-209 °C(lit.)
Density1.011
Flash Point150 °F

别名和识别编码

Chemical Name(+)-Borneol
Synonym (+)-莰醇,左旋龙脑,正龙脑; 内式-(1R)-1,7,7-三甲基双环[2.2.1]庚-2-醇;内型-(1R)-1,7,7-三甲基二环[2.2.1]庚-2-醇 d-Bornyl alcohol (+)-莰醇 (+)-BORNEOL 98% Bicyclo2.2.1heptan-2-ol, 1,7,7-trimethyl-, (1R,2S,4R)- (1r-endo)-1,7,7-trimethylbicyclo(2.2.1)heptan-2-ol ENDO-(1R)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-OL d-Borneol 7,7-trimethyl-(1r-endo)-bicyclo(2.2.1)heptan-2-o Bicyclo(2.2.1)heptan-2-ol, 1,7,7-trimethyl-, (1R-endo)- (+)-BORNEOL BORNEOL, (+)- (1R)-(+)-BORNEOL (+)-BORNEOL (1R,2S,4R)-borneol 龙脑 Asparagus Root D-龙脑 (+)-冰片 (+)-Borneol D-(+)-BORNEOL 冰片,2-茨醇,合成龙脑,内型-1,7,7-三甲基-二环[2.2.1]庚-2-醇 (1r,2s,4r)-(+)-borneo (1R)-endo-Borneol (1R-endo)-1,7,7-Trimethylbicyclo(2.2.1)heptan-2-ol 内式-(1R)-1,7,7-三甲基双环[2.2.1]庚-2-醇 [1R,2S,4R,(+)]-1,7,7-Trimethylbicyclo[2.2.1]heptan2-ol 樟醇,钓樟醇 内型-(1R)-1,7,7-三甲基二环[2.2.1]庚-2-醇
MDL NumberMFCD00066427
Beilstein Registry Number2038056
CAS Number464-43-7
EC Number207-352-6
PubChem Substance ID24866321
Chemical Name Translation(+)-冰片
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分类

  • {SNA} Alcohols, Artemisia vulgaris, Aspalathus linearis (Rooibos tea), Asymmetric Synthesis, Boswellia carterii, Chamaemelum nobile (Chamomile tea), Chemical Synthesis, Chiral Building Blocks, Citrus aurantium (Seville orange), Curcuma longa (Turmeric), Elettaria Cardamomum (Cardamom), Hypericum perforatum (St John's wort), Lavandula angustifolia (Lavendar tea), Ocimum basilicum (Basil), Organic Building Blocks, Phytochemicals by Plant (Food/Spice/Herb), Zingiber officinale (Ginger), 细胞生物学, 营养研究
  • {SNA} Alcohols,
  • {SNA} A - D, Additional Standards, Alphabetical Index of Phytochemical Standards, Analytical Standards, Angelica,

相关文献及参考

  • Merck 14 ,1338
  • Beil. 6 ,IV,281
  • FT-IR 2 (1), 236:A / Structure Index 1 , 21:A:7

安全信息

GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
Hazard statements
  • H228 Flammable solid 易燃固体
WGK Germany3
Signal word Warning
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSED7060000
Hazard Codes F F,Xn
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R11 Highly flammable 非常易燃
Storage condition 储存温度2-8℃
Packing GroupIII
Safety Statements
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
Hazard Class4.1
UN Number UN 1312 4.1/PG 3 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85KYAH "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals",
   11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989 Volume(issue)/page/year:
   11,204,1989

其他信息

  • Sigma Aldrich:464-43-7(sigmaaldrich)
  • 存在着正龙脑和异龙脑两个差向异构体，其中起主要作用的是正龙脑。龙脑为无色或白色半透明片状结晶，具有类似樟脑及薄荷的混合香气，易溶于乙醇，乙醚、石油醚、苯、甲苯、丙酮、萘烷、萘满、汽油等有机溶剂，微溶于水，易升华。
  • MOL 文件:464-43-7.mol

系列性分类

  1. Life Science 生命科学
  2. Nutrition Research 营养研究
  3. Phytochemicals by Plant (Food/Spice/Herb) - Nutrition Research
  4. Lavandula angustifolia (Lavendar tea) - Phytochemicals by Plant (Food/Spice/Herb)
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Life Sciences Standards - Chromatography
  5. Phytopharma Standards - Life Sciences Standards
  6. Standards by Plant Genus - Phytopharma Standards
  7. Zingiber - Standards by Plant Genus
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Alcohols - Organic Building Blocks

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