Dimethyl Vinylphosphonate 乙烯基膦酸二甲酯

CAS 4645-32-3 MFCD00015488

化学结构图

4645-32-3
SMILES: C=CP(=O)(OC)OC

化学属性

Mol. FormulaCH2=CHPO(OCH3)2
Mol. Weight136.09
Refractive indexn20/D 1.428
Boiling Point197-202 °C(lit.)
Density1.146 g/mL at 20 °C(lit.)
Flash Point101°(213°F)
TSCANo
Melting Point<-30°
Appearance colorless liq.
Stabilitystore cold

别名和识别编码

Chemical NameDimethyl Vinylphosphonate
CAS Number4645-32-3
PubChem Substance ID78376
EC Number225-076-4
Beilstein Registry Number1748827
MDL NumberMFCD00015488
Synonym Dimethyl vinylphosphonate {LY} Dimethyl vinylphosphonate {} {LY} Dimethyl vinylphosphonate {} {} {LY} Dimethyl vinylphosphonate {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl vinylphosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation乙烯基膦酸二甲酯
InChIKeyCQCXMYUCNSJSKG-UHFFFAOYSA-N
LabNetwork Molecule IDLN00239913
InChIInChI=1S/C4H9O3P/c1-4-8(5,6-2)7-3/h4H,1H2,2-3H3
Canonical SMILESCOP(=O)(C=C)OC
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphonates/Phosphinates, Phosphorus Compounds

相关文献及参考

  • 1. F. Nicotra et al. J. Chem. Soc., Chem. Commun. , 5, (1984)
  • 2. S. Mirza, A. Vasella Helv. Chim. Acta 67 , 1562, (1984)
  • 3. N. Minova et al. Bull. Chem. Soc. Jpn. 60 , 1761, (1987)
  • 4. J. Zygmunt Tetrahedron 41 , 4979, (1985)
  • Beil. 4 ,IV,3568

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Risk Statements
  • R46 May cause inheritable genetic damage 可能引起遗传基因损害
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Packing GroupIII
UN Number UN3265
Storage condition Light, Air & Moisture Sensitive

系列性分类