L-Hydroxyproline L-羟基脯氨酸

CAS 51-35-4 MFCD00064320

化学结构图

51-35-4
SMILES: O=C(O)[C@@H]1C[C@@H](O)CN1

化学属性

Mol. FormulaC5H9NO3
Mol. Weight131.13
Density1.395
Melting Point273
TSCAYes
SolubilitySoluble in water.

别名和识别编码

Chemical NameL-Hydroxyproline
CAS Number51-35-4
Alfabeta NameHYDROXYPYRROLIDINECARBOXYLICACID SR2442()----,
MDL NumberMFCD00064320
Synonym 4-Hydroxyproline Hydroxy-L-proline 反-4-羟基-L-脯氨酸;反式-4-羟基-L-脯氨酸;L-4-羟基脯氨酸;L-羟脯氨酸 Hydroxyproline L-羟基脯氨酸 (2S,4R)-(-)-4-Hydroxypyrrolidine-2-carboxylic acid trans-Hydroxyproline (2S,4R)-4-羟基吡咯烷-2-羧酸 4-Hydroxyproline Hydroxyproline Hyp Hyp (2S,4R)-4-羟基吡咯烷-2-羧酸 (2S,4R)-4-Hydroxypyrrolidine-2-carboxylic acid L-4-Hydroxyproline 反-4-羟基-L-脯氨酸;反式-4-羟基-L-脯氨酸;L-4-羟基脯氨酸 trans-L-Hydroxyproline L-羟脯氨酸 反式-4-羟基-L-脯氨酸 (2S,4R)-4-羟基吡咯烷-2-羧酸 Hyp 反-4-羟基-L-脯氨酸, 99+%
EC Number200-091-9
Beilstein Registry Number22(3/4)2047
PubChem Substance ID87570719
Merck Number4840
Chemical Name TranslationL-羟基脯氨酸
Reaxys-RN471933
LabNetwork Molecule IDLN00141965
InChIInChI=1S/C5H9NO3/c7-3-1-4(5(8)9)6-2-3/h3-4,6-7H,1-2H2,(H,8,9)/t3-,4+/m1/s1
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分类

  • {SNA} A - H, Aloe Vera, Amino Acids, Chemical Biology, Chemical Synthesis, Modified Amino Acids, Panax ginseng, Peptide Chemistry, Phytochemicals by Plant (Food/Spice/Herb), Proline Derivatives, Unnatural Amino Acids & Derivatives, 生化试剂, 细胞生物学, 营养研究
  • {SNA} Aloe Vera, Amino Acid, Amino Acids, Amino Acids and Vitamins, Chemical Biology, Chemical Synthesis, Panax ginseng, Peptide Chemistry, Phytochemicals by Plant (Food/Spice/Herb), Proline Derivatives, Unnatural Amino Acids & Derivatives,
  • {SNA} Aloe Vera,

产品应用

  • A versatile reagent for the synthesis of neuroexcitatory kainoids and antifungal echinocandins.

相关文献及参考

  • Chiral precursor for a wide variety of synthetic targets. For discussion of some examples, see: Tetrahedron, 52, 13803 (1996).
  • Merck: 14,4840
  • Merck: 14,4840 Beilstein:22(3/4)2047
  • [1]. Yi Y, et al. Biosynthesis of trans-4-hydroxyproline by recombinant strains of Corynebacterium glutamicum and Escherichia coli . BMC Biotechnol. 2014 May 19;14:44.

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSTW3586500
TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 10 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 372,75,1996

其他信息

  • Trans-4-Hydroxy-L-proline is a versatile reagent for the synthesis of neuroexcitatory kainoids and antifungal echinocandins. Also employed in the synthesis of chiral ligands for enantioselective ethylation of aldehydes. trans-4-Hydroxy-L-proline is a natural constituent of animal structural proteins such as collagen and elastin.

系列性分类


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